Free download The Vocabulary And Concepts Of Organic Chemistry By Milton Orchin 2nd Edition

2nd Edition

Authors of: The Vocabulary And Concepts Of Organic Chemistry By Milton Orchin 2nd Edition

Milton Orchin

Roger S. Macomber

Allan R. Pinhas

R Marshall Wilson

Table of Contents in The Vocabulary And Concepts Of Organic Chemistry By Milton Orchin 2nd Edition

Fundamental Theories and Bonding in Chemistry

1. Understanding Atomic Orbital Theory

Historical development and key principles

Quantum mechanical model of atoms

Wave functions and probability distributions

Shapes and orientations of atomic orbitals

The role of orbitals in chemical bonding

2. Bond Formation Between Adjacent Atoms: Localized and Molecular Orbital Theory

Overview of chemical bonding theories

Localized bonding and valence bond theory

Hybridization and its significance

Molecular orbital theory: bonding and antibonding orbitals

Comparison between localized and delocalized bonding

3. Delocalized (Multicenter) Bonding and Its Role in Chemistry

Understanding electron delocalization

Resonance structures and their significance

Multicenter bonding in aromatic compounds

Examples of delocalized bonding in inorganic chemistry

Impact of delocalization on stability and reactivity

Symmetry, Hydrocarbons, and Functional Groups

4. Symmetry Operations, Symmetry Elements, and Their Applications in Chemistry

Definitions of symmetry operations and symmetry elements

Point groups and their importance in molecular classification

Applications of symmetry in spectroscopy and molecular properties

Role of symmetry in determining polarity and optical activity

5. Classification and Properties of Hydrocarbons

Definition and general characteristics of hydrocarbons

Alkanes: structure, properties, and reactions

Alkenes and alkynes: unsaturation and reactivity

Aromatic hydrocarbons: benzene and polycyclic compounds

Comparison of hydrocarbon types in terms of stability and reactivity

6. Functional Groups: Major Classes of Organic Compounds

Definition and importance of functional groups

Alcohols, ethers, and phenols: structure and reactivity

Aldehydes and ketones: carbonyl functional groups

Carboxylic acids, esters, and their derivatives

Amines, nitriles, and sulfur-containing functional groups

Molecular Structure, Isomerism, and Stereochemistry

7. Molecular Structure, Isomers, Stereochemistry, and Conformational Analysis

Fundamental concepts of molecular structure

Structural isomerism: chain, position, and functional group isomers

Geometrical and optical isomerism

Chirality and enantiomeric relationships

Conformational analysis of cyclic and acyclic compounds

Advanced Topics in Organic Chemistry and Material Science

8. Synthetic Polymers: Structure, Properties, and Applications

Introduction to polymers and polymerization mechanisms

Addition vs. condensation polymers

Thermoplastic vs. thermosetting polymers

Common synthetic polymers and their industrial uses

Environmental impact and recycling of polymers

9. Organometallic Chemistry: Bonding, Reactivity, and Applications

Definition and scope of organometallic chemistry

Common organometallic compounds and their structures

Metal-carbon bonding and reactivity

Catalysis in industrial processes (e.g., Ziegler-Natta catalysts)

Applications of organometallic chemistry in synthesis

Analytical Chemistry and Energy Resources

10. Separation Techniques and Physical Properties of Compounds

Overview of separation techniques in chemistry

Chromatographic methods: gas chromatography, HPLC, TLC

Distillation, extraction, and crystallization techniques

Physical properties used in compound identification

Modern advancements in separation science

11. Fossil Fuels and Their Chemical Utilization in Industry

Composition and classification of fossil fuels

Petroleum refining and cracking processes

Coal gasification and liquefaction

Environmental concerns related to fossil fuel combustion

Alternatives to fossil fuels and sustainable energy solutions

Thermodynamics, Reaction Mechanisms, and Reactive Intermediates

12. Thermodynamics, Acids and Bases, and Chemical Kinetics

Basic principles of thermodynamics in chemistry

Entropy, enthalpy, and Gibbs free energy

Acid-base theories and pH calculations

Chemical kinetics: reaction rates and order

Activation energy and reaction mechanisms

13. Reactive Intermediates in Organic Reactions

Types of reactive intermediates: carbocations, carbanions, and radicals

Arynes and electron-deficient species

Stability and reactivity of intermediates

Role of reactive intermediates in organic synthesis

Experimental detection and characterization of intermediates

14. Classification and Mechanisms of Organic Reactions

Overview of major organic reaction types

Nucleophilic and electrophilic substitution reactions

Addition and elimination reactions

Pericyclic and radical reactions

Factors affecting reaction pathways

Spectroscopy and Analytical Techniques

15. Nuclear Magnetic Resonance (NMR) Spectroscopy: Principles and Applications

Introduction to NMR spectroscopy

Chemical shifts, spin-spin coupling, and integration

1H-NMR and 13C-NMR techniques

Interpretation of spectra for structural elucidation

Advanced techniques: 2D NMR and multinuclear NMR

16. Vibrational and Rotational Spectroscopy: Infrared, Microwave, and Raman Spectroscopy

Basic principles of vibrational spectroscopy

Interpretation of IR spectra and functional group identification

Microwave spectroscopy and molecular rotation

Raman spectroscopy and complementary applications

Spectroscopy in material science and biomolecular analysis

17. Mass Spectrometry: Ionization Methods and Structural Determination

Introduction to mass spectrometry

Ionization techniques: EI, CI, MALDI, ESI

Fragmentation patterns and molecular weight determination

High-resolution and tandem mass spectrometry

Applications in forensic, pharmaceutical, and environmental analysis

18. Electronic Spectroscopy and Photochemistry: Light-Matter Interactions

Principles of UV-Vis and fluorescence spectroscopy

Absorption and emission spectra

Photochemistry: excited-state reactions and energy transfer

Applications in solar energy and molecular electronics

Role of spectroscopy in studying reaction mechanisms

Indexes for Quick Reference

Name Index – Alphabetical listing of scientists, researchers, and contributors referenced in the book.

Compound Index – Index of all chemical compounds, reagents, and substances discussed.

General Index – Comprehensive listing of topics, keywords, and terms for easy navigation.

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