Fundamentals of molecular spectroscopy by Walter S. Struve
Free Download Fundamentals of molecular spectroscopy by Walter S. Struve
Fundamentals of molecular spectroscopy by Walter S. Struve
Authors:
Walter S. Struve
Department of Chemistry
Iowa State University Ames, Iowa
Table of Contents
CHAPTER 1
RADIATION-MATTER
INTERACTIONS 1
1.1 Classical Electrostatics of Molecules in Electric Fields
1.2 Quantum Theory of Molecules in Static Electric Fields
1.3 Classical Description of Molecules in Time-Dependent Fields
1.4 Time-Dependent Perturbation Theory of Radiation—Matter Interactions
1.5 Selection Rules for One-Photon Transitions
References
CHAPTER 2
ATOMIC SPECTROSCOPY
2.1 Hydrogenlike Spectra
2.2 Spin-Orbit Coupling
2.3 Structure of Many-Electron Atoms
2.4 Angular Momentum Coupling in Many-Electron Atoms
2.5 Many-Electron Atoms: Selection Rules and Spectra
2.6 The Zeeman Effect
References
CHAPTER 3
ROTATION AND VIBRATION IN DIATOMICS
3.1 The Born-Oppenheimer Principle
3.2 Diatomic Rotational Energy Levels and Spectroscopy
3.3 Vibrational Spectroscopy in Diatomics
3.4 Vibration—Rotation Spectra in Diatomics
3.5 Centrifugal Distortion
3.6 The Anharmonic Oscillator
References
CHAPTER 4
ELECTRONIC STRUCTURE AND SPECTRA IN DIATOMICS
4.1 Symmetry and Electronic Structure in Diatomics
4.2 Correlation of Molecular States with the Separated-Atom States
4.3 LCAO—MO Wave Functions in Diatomics
4.4 Electronic Spectra in Diatomics
4.5 Angular Momentum Coupling Cases
4.6 Rotational Fine Structure in Electronic Band Spectra
4.7 Potential Energy Curves from Electronic Band Spectra
References
Fundamentals of molecular spectroscopy by Walter S. Struve
CHAPTER 5
POLYATOMIC ROTATIONS
5.1 Classical Hamiltonian and Symmetry Classification of Rigid Rotors
5.2 Rigid Rotor Angular Momenta
5.3 Rigid Rotor States and Energy Levels
5.4 Selection Rules for Pure Rotational Transitions
5.5 Microwave Spectroscopy of Polyatomic Molecules
References
CHAPTER 6
POLYATOMIC VIBRATIONS
6.1 Classical Treatment of Vibrations in Polyatomic
6.2 Normal Coordinates
6.3 Internal Coordinates and the – FG-Matrix Method
6.4 Symmetry Classification of Normal Modes
6.5 Selection Rules in Vibrational Transitions
6.6 Rotational Fine Structure of Vibrational Bands
6.7 Breakdown of the Normal Mode Approximation
References
CHAPTER 7
ELECTRONIC SPECTROSCOPY OF POLYATOMIC MOLECULES
7.1 Triatomic Molecules
7.2 Aromatic Hydrocarbons
7.3 Quantitative Theories of Vibronic Coupling
7.4 Radiationless Relaxation in Isolated Polyatomic
References
CHAPTER 8
SPECTRAL LINE SHAPES AND OSCILLATOR STRENGTHS
8.1 Electric Dipole Correlation Functions
8.2 Lifetime Broadening
8.3 Doppler Broadening and Voigt Profiles
8.4 Einstein Coefficients
8.5 Oscillator Strengths
References
CHAPTER 9
LASERS
9.1 Population Inversions and Lasing Criteria
9.2 The He/Ne and Dye Lasers
9.3 Axial Mode Structure and Single-Mode Selection
9.4 Mode-Locking and Ultrashort Laser Pulses
References
Fundamentals of molecular spectroscopy by Walter S. Struve
CHAPTER 10
TWO-PHOTON PROCESSES
10.1 Theory of Two-Photon Processes
10.2 Two-Photon Absorption
10.3 Raman Spectroscopy
References
CHAPTER
NONLINEAR OPTICS
11.1 Diagrammatic Perturbation Theory
11.2 Second-Harmonic Generation
11.3 Coherent Anti-Stokes Raman Scattering
References
APPENDIX A FUNDAMENTAL CONSTANTS
APPENDIX B ENERGY CONVERSION FACTORS
APPENDIX C MULTIPOLE EXPANSIONS OF CHARGE DISTRIBUTIONS
APPENDIX D BEER’S LAW
APPENDIX E ADDITION OF TWO ANGULAR MOMENTA
APPENDIX F GROUP CHARACTER TABLES AND DIRECT PRODUCTS
APPENDIX G TRANSFORMATION BETWEEN LABORATORY-FIXED AND CENTER-OF-MASS COORDINATES IN A DIATOMIC MOLECULE
AUTHOR INDEX
SUBJECT INDEX
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