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Fundamentals of molecular spectroscopy by Walter S. Struve

Fundamentals of molecular spectroscopy by Walter S. Struve

Fundamentals of molecular spectroscopy by Walter S. Struve

Free Download Fundamentals of molecular spectroscopy by Walter S. Struve

Fundamentals of molecular spectroscopy by Walter S. Struve

Authors:
Walter S. Struve
Department of Chemistry
Iowa State University Ames, Iowa

 

Table of Contents

CHAPTER 1

RADIATION-MATTER

INTERACTIONS 1

1.1 Classical Electrostatics of Molecules in Electric Fields 

1.2 Quantum Theory of Molecules in Static Electric Fields 

1.3 Classical Description of Molecules in Time-Dependent Fields 

1.4 Time-Dependent Perturbation Theory of Radiation—Matter Interactions 

1.5 Selection Rules for One-Photon Transitions 

References

CHAPTER 2

ATOMIC SPECTROSCOPY 

2.1 Hydrogenlike Spectra 

2.2 Spin-Orbit Coupling 

2.3 Structure of Many-Electron Atoms 

2.4 Angular Momentum Coupling in Many-Electron Atoms 

2.5 Many-Electron Atoms: Selection Rules and Spectra 

2.6 The Zeeman Effect

References

CHAPTER 3

ROTATION AND VIBRATION IN DIATOMICS

3.1 The Born-Oppenheimer Principle

3.2 Diatomic Rotational Energy Levels and Spectroscopy

3.3 Vibrational Spectroscopy in Diatomics

3.4 Vibration—Rotation Spectra in Diatomics

3.5 Centrifugal Distortion

3.6 The Anharmonic Oscillator

References

CHAPTER 4

ELECTRONIC STRUCTURE AND SPECTRA IN DIATOMICS 

4.1 Symmetry and Electronic Structure in Diatomics 

4.2 Correlation of Molecular States with the Separated-Atom States 

4.3 LCAO—MO Wave Functions in Diatomics 

4.4 Electronic Spectra in Diatomics 

4.5 Angular Momentum Coupling Cases 

4.6 Rotational Fine Structure in Electronic Band Spectra 

4.7 Potential Energy Curves from Electronic Band Spectra 

References 

Fundamentals of molecular spectroscopy by Walter S. Struve

CHAPTER 5

POLYATOMIC ROTATIONS 

5.1 Classical Hamiltonian and Symmetry Classification of Rigid Rotors 

5.2 Rigid Rotor Angular Momenta 

5.3 Rigid Rotor States and Energy Levels 

5.4 Selection Rules for Pure Rotational Transitions 

5.5 Microwave Spectroscopy of Polyatomic Molecules 

References 

CHAPTER 6

POLYATOMIC VIBRATIONS 

6.1 Classical Treatment of Vibrations in Polyatomic 

6.2 Normal Coordinates 

6.3 Internal Coordinates and the – FG-Matrix Method 

6.4 Symmetry Classification of Normal Modes 

6.5 Selection Rules in Vibrational Transitions 

6.6 Rotational Fine Structure of Vibrational Bands 

6.7 Breakdown of the Normal Mode Approximation 

References 

CHAPTER 7

ELECTRONIC SPECTROSCOPY OF POLYATOMIC MOLECULES 

7.1 Triatomic Molecules 

7.2 Aromatic Hydrocarbons 

7.3 Quantitative Theories of Vibronic Coupling 

7.4 Radiationless Relaxation in Isolated Polyatomic 

References 

CHAPTER 8

SPECTRAL LINE SHAPES AND OSCILLATOR STRENGTHS 

8.1 Electric Dipole Correlation Functions 

8.2 Lifetime Broadening 

8.3 Doppler Broadening and Voigt Profiles 

8.4 Einstein Coefficients 

8.5 Oscillator Strengths 

References 

CHAPTER 9

LASERS 

9.1 Population Inversions and Lasing Criteria 

9.2 The He/Ne and Dye Lasers 

9.3 Axial Mode Structure and Single-Mode Selection 

9.4 Mode-Locking and Ultrashort Laser Pulses 

References 

Fundamentals of molecular spectroscopy by Walter S. Struve

CHAPTER 10

TWO-PHOTON PROCESSES 

10.1 Theory of Two-Photon Processes 

10.2 Two-Photon Absorption 

10.3 Raman Spectroscopy 

References 

CHAPTER

NONLINEAR OPTICS 

11.1 Diagrammatic Perturbation Theory 

11.2 Second-Harmonic Generation 

11.3 Coherent Anti-Stokes Raman Scattering 

References 

APPENDIX A FUNDAMENTAL CONSTANTS 

APPENDIX B ENERGY CONVERSION FACTORS 

APPENDIX C MULTIPOLE EXPANSIONS OF CHARGE DISTRIBUTIONS 

APPENDIX D BEER’S LAW 

APPENDIX E ADDITION OF TWO ANGULAR MOMENTA 

APPENDIX F GROUP CHARACTER TABLES AND DIRECT PRODUCTS

APPENDIX G TRANSFORMATION BETWEEN LABORATORY-FIXED AND CENTER-OF-MASS COORDINATES IN A DIATOMIC MOLECULE 

AUTHOR INDEX 

SUBJECT INDEX 

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