Free download Reaction Mechanisms, Pericyclic Reactions, Organic Photochemistry and Stereochemistry By Vardhman Mahaveer Open University

Authors of:  Reaction Mechanisms, Pericyclic Reactions, Organic Photochemistry and Stereochemistry By Vardhman Mahaveer Open University

Vardhman Mahaveer Open University

Table of Contents in Reaction Mechanisms, Pericyclic Reactions, Organic Photochemistry and Stereochemistry By Vardhman Mahaveer Open University

Unit -1 Reaction Intermediates – Formation, stability, structure,

detection and reaction of carbonium ions, carbanions and free radicals

Unit -2 Reaction Intermediates-

Unit -3 Molecular Rearrangements-I

Unit -4 Molecular Rearrangements – II

Unit -5 Elimination Reaction

Unit -6 Molecular Orbitals and Their Symmetry Properties

Unit -7 Classification and stereochemistry of pericyclic reactions:

Classification of pericyclic reactions. Woodward￾Hoffmann correlation diagrams. FMO and PMO approach

Unit -8 Analysis of Electrocyclic Reactions

Unit -9 Analysis of cycloaddition: Cycloaddition, antarafacial,

suprofacial additions, 4n and 4n+2 systems. 2+2 addition

of Ketenes, 1,3-dipolar cycloadditions & cheletropic reactions

Unit -10 Analysis of Sigmatropic Reactions

Unit -11 Electronic Transitions

Unit -12 Photochemistry of Carbonyl Compound

Unit -13 Photochemistry of Alkenes and Dienes

Unit -14 Photochemistry of Aromatic Compounds: Isomerisation, additions and substitutions

Unit -15 Miscellaneous Photochemical Reactions

Unit -16 Conformations of Some Acyclic Molecules

Unit -17 Confirmation of some cyclic molecules Cyclobutanes,

Cyclopentane and Cyclohexane and Monosubsituted Cyclohexane

Unit -18 Conformations of Di-Substituted Cyclohexanes

Unit -19 Conformations of A Few Other Monocyclic and Bicyclic Systems

Unit -20 Conformation and Reactivity

The study of organic chemistry encompasses a wide array of topics, each delving into the intricacies of molecular behavior and reactivity. In this comprehensive exploration, we embark on a journey through various units, dissecting the formation, stability, structure, detection, and reaction mechanisms of fundamental intermediates, as well as the intricate symmetries and transitions that govern molecular rearrangements and reactions.

Unit 1: Reaction Intermediates

This unit focuses on the formation, stability, structure, detection, and reaction pathways of carbonium ions, carbanions, and free radicals, crucial intermediates in organic transformations.

Unit 2: Reaction Intermediates

Continuing our examination of reaction intermediates, this unit delves deeper into their role and behavior in chemical reactions.

Unit 3: Molecular Rearrangements I

Here, we explore molecular rearrangements, studying their mechanisms and implications in organic synthesis.

Unit 4: Molecular Rearrangements II

Building upon the concepts introduced in the previous unit, this section further explores molecular rearrangements, expanding our understanding of their diverse manifestations.

Unit 5: Elimination Reaction

This unit investigates elimination reactions, elucidating their mechanisms and applications in organic chemistry.

Unit 6: Molecular Orbitals and Their Symmetry Properties

A profound understanding of molecular orbitals and their symmetries is essential for comprehending various chemical phenomena, and this unit aims to provide a comprehensive overview.

Unit 7: Classification and Stereochemistry of Pericyclic Reactions

Pericyclic reactions constitute a class of reactions with unique stereochemical characteristics. In this unit, we classify pericyclic reactions and explore their stereochemistry through Woodward-Hoffmann correlation diagrams and the Frontier Molecular Orbital (FMO) and Pericyclic Molecular Orbital (PMO) approaches.

Unit 8: Analysis of Electrocyclic Reactions

Electrocyclic reactions represent a fascinating area of study in organic chemistry. This unit offers an in-depth analysis of their mechanisms and applications.

Unit 9: Analysis of Cycloaddition

Cycloaddition reactions are pivotal in organic synthesis, and this unit scrutinizes their mechanisms, including antarafacial and suprafacial additions, as well as systems involving 4n and 4n+2 electrons. Additionally, it covers 2+2 addition reactions of ketenes, 1,3-dipolar cycloadditions, and cheletropic reactions.

Unit 10: Analysis of Sigmatropic Reactions

Sigmatropic rearrangements play a significant role in organic synthesis, and this unit provides a thorough analysis of their mechanisms and applications.

Unit 11: Electronic Transitions

Understanding electronic transitions is crucial in comprehending various chemical processes. This unit explores the principles underlying electronic transitions in organic molecules.

Unit 12: Photochemistry of Carbonyl Compounds

The photochemistry of carbonyl compounds involves intricate processes that influence their reactivity and behavior. This unit delves into the photochemical reactions of carbonyl compounds, elucidating their mechanisms and outcomes.

Unit 13: Photochemistry of Alkenes and Dienes

Alkenes and dienes exhibit unique photochemical behaviors, which are explored in this unit, shedding light on their photochemical reactions and applications.

Unit 14: Photochemistry of Aromatic Compounds

Aromatic compounds undergo diverse photochemical reactions, including isomerization, additions, and substitutions. This unit investigates these reactions and their significance in organic synthesis.

Unit 15: Miscellaneous Photochemical Reactions

This unit explores additional photochemical reactions not covered in previous sections, providing a comprehensive overview of their mechanisms and applications.

Unit 16: Conformations of Some Acyclic Molecules

Conformational analysis is essential for understanding the behavior of organic molecules. This unit focuses on the conformational analysis of selected acyclic molecules.

Unit 17: Conformation of Some Cyclic Molecules

Cyclic molecules exhibit unique conformational characteristics, which are explored in this unit, with a focus on cyclobutanes, cyclopentane, and cyclohexane, as well as monosubstituted cyclohexane.

Unit 18: Conformations of Di-Substituted Cyclohexanes

The conformational analysis of disubstituted cyclohexanes presents intriguing challenges, which are addressed in this unit through a detailed examination of their conformational landscapes.

Unit 19: Conformations of a Few Other Monocyclic and Bicyclic Systems

Expanding our scope, this unit investigates the conformational behavior of additional monocyclic and bicyclic systems, providing insights into their structural preferences and reactivity.

Unit 20: Conformation and Reactivity

In the final unit, we explore the interplay between molecular conformation and reactivity, highlighting the profound influence of molecular geometry on chemical behavior.

Through this comprehensive journey, we aim to equip learners with a deep understanding of the principles, mechanisms, and applications of organic chemistry, enabling them to navigate and contribute to this vibrant field with confidence and proficiency.

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