Free download Physical Chemistry Vol. 1 by Dr. J. N. Gurtu

Volume 1

Authors of: Physical Chemistry Vol. 1 by Dr. J. N. Gurtu

Dr. J. N. Gurtu

Aayushi Gurtu

Table of Contents in Physical Chemistry Vol. 1 by Dr. J. N. Gurtu

1. MATHEMATICAL CONCEPTS

Logarithms

Common logarithms and use of four figure log tables

Antilogarithms

linear graphs and slopes

Curve sketching 8

Functions of a real variable

Differentiation

Partial differentiations

Maxima and minima

Integration

Permutation and combination

Probability

Exercises

2. COMPUTERS-FUNDAMENTALS AND WORKING

Need for computer learning

Different components of a computer

Hardware and software

The binary number system

Programming

Computer programming languages

Operating systems

Exercises

3. GASEOUS STATE

Gas laws

Kinetic theory of gases  

Kinetic energy and temperature of a gas  

Maxwell’s law of distribution of molecular velocities

Molecular velocity

Expansivity and compressibility 130

Mean free path

Collision diameter

Collision number  

Collision frequency

Viscosity of gases

Heat capacity of gases

Real gases and ideal gases   

Deviations of real gases from the ideal gas laws

vander Waals equation of state  

Critical phenomenon

Law of corresponding states

Other equations of state

Liquefaction of gases

Exercises

4. LIQUID STATE

Gaseous, liquid and solid states  

Structural differences between solids, liquids and gases

Characteristic properties of liquids

Intermolecular forces in liquids

Structure of liquids

Liquid crystals  

Thermography

Exercises

5. SOLID STATE

Classification of solids

What is a crystal?  

External features of a crystal  

Laws of crystallography  

Point groups

Crystallographic terms

Crystal systems

Space lattice  

Unit cell

Coordination number

Calculation of number of particles in a unit cell

Hauy’s law of rational intercepts or indices  

Weiss indices

Miller indices

Bravais space lattices

Interplanar distances or separation between lattice planes

Internal structrue of crystals

Structure of crystals

Binding forces in crystals

Defects in crystals

Thelma I defects and semi-conductors

Applications of X-ray analysis

Isomorphism  

Morphotropism and polymorphism

Closed packed structure

Closed packing of identical spheres

Interstitial sites in closed packed structure

Size of interstitial sites in ionic crystals

Ionic radii

Superconductivity

Lattice energy of ionic crystals

Born-Haber cycle

Exercises  

6. COLLOIDAL STATE

Introduction

Colloidal solutions

Size of colloidal particles  

DiFFerences between suspension, colloidal solution and true solution

Types and classiFication of colloidal systems

Preparation of colloidal solutions  

PuriFication of sols

General properties of colloidal systems  

Optical properties of colloidal solutions’

Kinetic properties of colloidal solutions

Coagulation

Protection

Stability of sols

Electrical properties of colloidal solutions

Origin of charge

Electrical double layer

Determination of size of colloidal particles

SurFactants

Emulsions

Gels

Sol-gel transFormation  

Thixotropy  

General applications of colloids  

Exercises

7. CHEMICAL KINETICS

Introduction

Reaction velocity

Velocity or rate constant

Order of reaction

Molecularity

Pseudo-molecular reactions

Zero order reactions

First order reactions

Second order reactions

Third order reactions

Half life of systems involving more than one reactant reactions

Negative order reactions

Determination of order of reaction

Experimental methods to study reaction kinetics

Composite reactions (complex reactions)

Arrhenius equation

Theories of reaction rates

Exercises

8. CATALYSIS

Catalyst and catalysis

Types of catalysis

Classification of catalysis

Characteristics of catalytic reactions

Catalytic promoters

Catalytic poisons

Theories of catalysis

Biochemical or enzyme catalysis

Acid-base catalysis

Industrial applications of catalysts

Exercises

SUB..JECT INDEX

LOG AND ANTILOG TABLES

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