Inorganic Chemistry by Gary L. Miessler 5th Edition
Free Download Inorganic Chemistry by Gary L. Miessler 5th Edition
5th Edition
Authors of: Inorganic Chemistry by Gary L. Miessler 5th Edition
Gary L. Miessler
Paul J. Fischer
Donald A. Tarr
Table of Contents in Inorganic Chemistry by Gary L. Miessler 5th Edition
1.1 What Is Inorganic Chemistry?
1.2 Contrasts with Organic Chemistry
1.3 The History of Inorganic Chemistry
1.4 Perspective
General References
Chapter 2 Atomic Structure
2.1 Historical Development of Atomic Theory
2.1.1 The Periodic Table
2.1.2 Discovery of Subatomic Particles and the Bohr Atom
2.2 The Schrödinger Equation
2.2.1 The Particle in a Box
2.2.2 Quantum Numbers and Atomic Wave Functions
2.2.3 The Aufbau Principle
2.2.4 Shielding
2.3 Periodic Properties of Atoms
2.3.1 Ionization Energy
2.3.2 Electron Affinity
2.3.3 Covalent and Ionic Radii
General References • Problems
Chapter 3 Simple Bonding Theory
3.1 Lewis Electron-Dot Diagrams
3.1.1 Resonance
3.1.2 Higher Electron Counts
3.1.3 Formal Charge
3.1.4 Multiple Bonds in Be and B Compounds
3.2 Valence Shell Electron-Pair Repulsion
3.2.1 Lone-Pair Repulsion
3.2.2 Multiple Bonds
3.2.3 Electronegativity and Atomic Size Effects
3.2.4 Ligand Close Packing
3.3 Molecular Polarity
3.4 Hydrogen Bonding
General References • Problems
Chapter 4 Symmetry and Group Theory
4.1 Symmetry Elements and Operations
4.2 Point Groups
4.2.1 Groups of Low and High Symmetry
4.2.2 Other Groups
4.3 Properties and Representations of Groups
4.3.1 Matrices
4.3.2 Representations of Point Groups
4.3.3 Character Tables
4.4 Examples and Applications of Symmetry
4.4.1 Chirality
4.4.2 Molecular Vibrations
General References • Problems
Chapter 5 Molecular Orbitals
5.1 Formation of Molecular Orbitals from Atomic Orbitals
5.1.1 Molecular Orbitals from s Orbitals
5.1.2 Molecular Orbitals from p Orbitals
5.1.3 Molecular Orbitals from d Orbitals
5.1.4 Nonbonding Orbitals and Other Factors
5.2 Homonuclear Diatomic Molecules
5.2.1 Molecular Orbitals
5.2.2 Orbital Mixing
5.2.3 Diatomic Molecules of the First and Second Periods
5.2.4 Photoelectron Spectroscopy
5.3 Heteronuclear Diatomic Molecules
5.3.1 Polar Bonds
5.3.2 Ionic Compounds and Molecular Orbitals
5.4 Molecular Orbitals for Larger Molecules
5.4.1 FHF –
5.4.2 CO 2
5.4.3 H 2 O
5.4.4 NH 3
5.4.5 CO 2 Revisited with Projection Operators
5.4.6 BF 3
5.4.7 Hybrid Orbitals
General References • Problems
Chapter 6 Acid–Base and Donor–Acceptor Chemistry
6.1 Acid–Base Models as Organizing Concepts
6.1.1 History of Acid–Base Models
6.2 Arrhenius Concept
6.3 Brønsted–Lowry Concept
6.3.1 Nonaqueous Solvents and Acid–Base Strength
6.3.2 Brønsted–Lowry Superacids
6.3.3 Thermodynamic Measurements in Solution
6.3.4 Brønsted–Lowry Gas Phase Acidity and Basicity
6.3.5 Brønsted–Lowry Superbases
6.3.6 Trends in Brønsted–Lowry Basicity
6.3.7 Brønsted–Lowry Acid Strength of Binary Hydrogen Compounds
6.3.8 Brønsted–Lowry Strength of Oxyacids
6.3.9 Brønsted–Lowry Acidity of Aqueous Cations
6.4 Lewis Acid–Base Concept and Frontier Orbitals
6.4.1 Frontier Orbitals and Acid–Base Reactions
6.4.2 Spectroscopic Support for Frontier Orbital Interactions
6.4.3 Quantifi cation of Lewis Basicity
6.4.4 The BF3 Affi nity Scale for Lewis Basicity
6.4.5 Halogen Bonds
6.4.6 Inductive Effects on Lewis Acidity and Basicity
6.4.7 Steric Effects on Lewis Acidity and Basicity
6.4.8 Frustrated Lewis Pairs
6.5 Intermolecular Forces
6.5.1 Hydrogen Bonding
6.5.2 Receptor–Guest Interactions
6.6 Hard and Soft Acids and Bases
6.6.1 Theory of Hard and Soft Acids and Bases
6.6.2 HSAB Quantitative Measures
General References • Problems
Chapter 7 The Crystalline Solid State
Chapter 8 Chemistry of the Main Group Elements
8.1 General Trends in Main Group Chemistry
Chapter 9 Coordination Chemistry I: Structures and Isomers
Chapter 10 Coordination Chemistry II: Bonding
Chapter 11 Coordination Chemistry III: Electronic Spectra
Chapter 12 Coordination Chemistry IV: Reactions and Mechanisms
Chapter 13 Organometallic Chemistry
Chapter 14 Organometallic Reactions and Catalysis
Chapter 15 Parallels between Main Group and Organometallic Chemistry
Appendix A Answers to Exercises
Appendix B Useful Data
Appendix C Character Tables
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