Organic Chemistry Structure and Function by Peter Vollhardt 6th Ed
Free Download Organic Chemistry Structure and Function by Peter Vollhardt 6th Ed
6th Edition
Authors of: Organic Chemistry Structure and Function by Peter Vollhardt 6th Edition
Peter Vollhardt
Neil Schore
Table of Contents in Organic Chemistry Structure and Function by Peter Vollhardt 6th Edition
PREFACE: A User’s Guide to Organic Chemistry:
Structure and Function
1 STRUCTURE AND BONDING IN ORGANIC MOLECULES
1-1 The Scope of Organic Chemistry: An Overview: Chemical Highlight 1-1 Urea: From Urine to Wöhler’s Synthesis to Industrial Fertilizer
1-2 Coulomb Forces: A Simplified View of Bonding
1-3 Ionic and Covalent Bonds: The Octet Rule
1-4 Electron-Dot Model of Bonding: Lewis Structures
1-5 Resonance Forms
1-6 Atomic Orbitals: A Quantum Mechanical Description of Electrons Around the Nucleus
1-7 Molecular Orbitals and Covalent Bonding
1-8 Hybrid Orbitals: Bonding in Complex Molecules
1-9 Structures and Formulas of Organic Molecules
Chapter Integration Problems
Important Concepts
Problems
2 STRUCTURE AND REACTIVITY
2-1 Kinetics and Thermodynamics of Simple Chemical Processes
2-2 Acids and Bases; Electrophiles and Nucleophiles; Using Curved “Electron-Pushing” Arrows
Chemical Highlight 2-1 Stomach Acid and Food Digestion
2-3 Functional Groups: Centers of Reactivity
2-4 Straight-Chain and Branched Alkanes
2-5 Naming the Alkanes
2-6 Structural and Physical Properties of Alkanes
Chemical Highlight 2-2 “Sexual Swindle” by Means of Chemical Mimicry
2-7 Rotation about Single Bonds: Conformations
2-8 Rotation in Substituted Ethanes
Chapter Integration Problems
Important Concepts
Problems
3 REACTIONS OF ALKANES
3-1 Strength of Alkane Bonds: Radicals
3-2 Structure of Alkyl Radicals: Hyperconjugation
3-3 Conversion of Petroleum: Pyrolysis
Chemical Highlight 3-1 Sustainability and the Needs of the 21st Century: “Green” Chemistry
3-4 Chlorination of Methane: The Radical Chain Mechanism
3-5 Other Radical Halogenations of Methane
3-6 Chlorination of Higher Alkanes: Relative
Reactivity and Selectivity
3-7 Selectivity in Radical Halogenation with Fluorine and Bromine
3-8 Synthetic Radical Halogenation
Chemical Highlight 3-2 Chlorination, Chloral, and DDT
3-9 Synthetic Chlorine Compounds and the Stratospheric Ozone Layer
3-10 Combustion and the Relative Stabilities of Alkanes
Chapter Integration Problems
Important Concepts
Problems
4 CYCLOALKANES
4-1 Names and Physical Properties of Cycloalkanes
4-2 Ring Strain and the Structure of Cycloalkanes
4-3 Cyclohexane: A Strain-Free Cycloalkane
4-4 Substituted Cyclohexanes
4-5 Larger Cycloalkanes
4-6 Polycyclic Alkanes
Chemical Highlight 4-1 Cyclohexane, Adamantane, and Diamandoids: Diamond “Molecules”
4-7 Carbocyclic Products in Nature
Chemical Highlight 4-2 Cholesterol: How Is It Bad and How Bad Is It?
Chemical Highlight 4-3 Controlling Fertility: From “the Pill” to RU-486
Chapter Integration Problems
Important Concepts
Problems
5 STEREOISOMERS
5-1 Chiral Molecules
Chemical Highlight 5-1 Chiral Substances in Nature
5-2 Optical Activity
5-3 Absolute Configuration: R – S Sequence Rules
5-4 Fischer Projections
Chemical Highlight 5-2 Absolute Configuration: A Historical Note
5-5 Molecules Incorporating Several Stereocenters: Diastereomers
Chemical Highlight 5-3 Stereoisomers of Tartaric Acid
5-6 Meso Compounds
5-7 Stereochemistry in Chemical Reactions
Chemical Highlight 5-4 Chiral Drugs: Racemic or
Enantiomerically Pure?
Chemical Highlight 5-5 Why Is Nature “Handed”?
5-8 Resolution: Separation of Enantiomers
Chapter Integration Problems
Important Concepts
Problems
6 PROPERTIES AND REACTIONS OF HALOALKANES
7 FURTHER REACTIONS OF HALOALKANES
8 HYDROXY FUNCTIONAL GROUP: Alcohol
9 FURTHER REACTIONS OF ALCOHOLS AND THE CHEMISTRY OF ETHERS
10 USING NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY TO DEDUCE STRUCTURE
11 ALKENES; INFRARED SPECTROSCOPY AND MASS SPECTROMETRY
INTERLUDE: Solving Problems in Organic Chemistry
12 REACTIONS OF ALKENES
13 ALKYNES
14 DELOCALIZED PI SYSTEMS
INTERLUDE: A Summary of Organic Reaction Mechanisms
15 BENZENE AND AROMATICITY
16 ELECTROPHILIC ATTACK ON DERIVATIVES OF BENZENE
17 ALDEHYDES AND KETONES
18 ENOLS, ENOLATES, AND THE ALDOL CONDENSATION
19 CARBOXYLIC ACIDS
20 CARBOXYLIC ACID DERIVATIVES
21 AMINES AND THEIR DERIVATIVES
22 CHEMISTRY OF BENZENE SUBSTITUENTS
23 ESTER ENOLATES AND THE CLAISEN CONDENSATION
24 CARBOHYDRATES: Polyfunctional Compounds in Nature
25 HETEROCYCLES: Heteroatoms in Cyclic Organic Compounds
26 AMINO ACIDS, PEPTIDES, PROTEINS, AND NUCLEIC
ACIDS: Nitrogen-Containing Polymers in Nature
MCAT® Questions MCAT-1
Answers to Exercises A-1
Photograph Credits C-1
Index I-1
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