Free download Chemistry for JEE Main & Advanced 2nd Edition d and f-block Elements

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Table of Contents in Chemistry for JEE Main & Advanced 2nd Edition d and f-block Elements

PART 1: INTRODUCTION TO d- AND f-BLOCK ELEMENTS

Overview of the d- and f-block Elements

1.1 Periodic Table Position of d- and f-block Elements

1.2 General Characteristics of d-Block Elements (Transition Elements)

1.3 General Characteristics of f-Block Elements (Inner Transition Elements)

1.4 Comparison of d-block and f-block Elements

1.5 Role of d- and f-block Elements in Industry and Daily Life

Electronic Configurations of d- and f-Block Elements

2.1 Aufbau Principle and d-Block Elements

2.2 Electron Configurations of 3d, 4d, and 5d Series

2.3 Electron Configurations of Lanthanides and Actinides (f-block)

2.4 Anomalous Configurations (e.g., Chromium and Copper)

2.5 Consequences of Electronic Configurations (Magnetic Properties, Colors, etc.)

PART 2: d-BLOCK ELEMENTS (TRANSITION ELEMENTS)

3. General Properties of d-Block Elements

3.1 Variable Oxidation States

3.2 Trends in Physical Properties (Density, Melting/Boiling Points, Ionization Energy)

3.3 Color and Spectra of Transition Metal Compounds

3.4 Catalytic Properties of d-block Elements

3.5 Magnetic Properties (Paramagnetism, Diamagnetism, Ferromagnetism)

3.6 Complex Formation (Ligands, Coordination Numbers, and Complexes)

3.7 Interstitial Compounds and Alloys

Chemistry of 3d Series Elements (Sc to Zn)

4.1 Detailed Study of Each Element (Sc, Ti, V, Cr, Mn, Fe, Co, Ni, Cu, Zn)

4.2 Unique Properties of Manganese (Mn), Iron (Fe), and Copper (Cu)

4.3 Trends in Properties (Oxidation States, Color, Catalytic Behavior)

4.4 Important Compounds of 3d Elements (KMnO₄, K₂Cr₂O₇, FeCl₃, CuSO₄)

Chemistry of 4d and 5d Series Elements

5.1 Overview of 4d and 5d Series (Y to Ag, Hf to Hg)

5.2 Trends in Properties (Size, Ionization Energy, etc.)

5.3 Unique Features of Silver (Ag), Palladium (Pd), Platinum (Pt), and Gold (Au)

5.4 Key Compounds of 4d and 5d Elements (AgNO₃, PdCl₂, PtCl₄)

Important Reactions of d-Block Elements

6.1 Redox Reactions of d-block Elements

6.2 Disproportionation Reactions (e.g., MnO₄⁻, Cr₂O₇²⁻)

6.3 Important Name Reactions (e.g., Wacker Process, Kroll Process)

6.4 Reaction Mechanisms (Catalysis by d-block Elements)

PART 3: f-BLOCK ELEMENTS (INNER TRANSITION ELEMENTS)

7. Introduction to Lanthanides (4f Series) and Actinides (5f Series)

7.1 Position in Periodic Table and General Features

7.2 Overview of Lanthanides and Actinides

7.3 Discovery and Naming of f-block Elements

Electronic Configuration and Oxidation States of f-Block Elements

8.1 Aufbau Principle and f-Block Elements

8.2 Electronic Configurations of Lanthanides (La to Lu)

8.3 Electronic Configurations of Actinides (Ac to Lr)

8.4 Oxidation States and Their Stability

Properties of Lanthanides

9.1 Lanthanide Contraction and Its Consequences

9.2 Color and Spectra of Lanthanide Compounds

9.3 Magnetic Properties of Lanthanides

9.4 Complex Formation and Coordination Behavior

Properties of Actinides

10.1 Actinides vs Lanthanides: Similarities and Differences

10.2 Oxidation States of Actinides (Thorium, Uranium, Plutonium)

10.3 Actinide Contraction and Its Effects

10.4 Nuclear Chemistry of Actinides (Radioactivity, Nuclear Fuel Cycle)

Separation of Lanthanides and Actinides

11.1 Principles of Separation of Lanthanides (Ion Exchange and Solvent Extraction)

11.2 Separation of Actinides from Nuclear Waste

PART 4: APPLICATIONS OF d- AND f-BLOCK ELEMENTS

12. Applications of d-Block Elements

12.1 Use in Alloys (Steel, Stainless Steel, Nichrome)

12.2 Role in Catalysis (Haber Process, Contact Process)

12.3 Use in Electronics and Magnetic Materials

12.4 Medicinal Uses (Platinum-based Cancer Drugs)

Applications of f-Block Elements

13.1 Use of Lanthanides in Glass, Ceramics, and Optical Devices

13.2 Role of Actinides in Nuclear Energy (Uranium and Plutonium)

13.3 Medical and Industrial Uses of Actinides (Radioactive Tracers, Cancer Therapy)

PART 5: ADVANCED TOPICS AND PROBLEM-SOLVING STRATEGIES

14. Coordination Compounds of d- and f-Block Elements

14.1 Key Concepts of Coordination Compounds (IUPAC Naming, Types of Ligands)

14.2 Hybridization, Geometry, and Crystal Field Theory (CFT)

14.3 Color, Magnetic Behavior, and Stability of Complexes

14.4 Isomerism in Coordination Compounds (Geometrical, Optical, Linkage)

JEE Problem-Solving Techniques for d- and f-Block Elements

15.1 Important Tips for JEE (Main & Advanced)

15.2 Concept-Based Problems (MCQs, Assertion-Reason, Passage-Based)

15.3 Calculation-Based Problems (Oxidation State, Molar Mass, etc.)

15.4 Strategy for Solving Complex Numerical Problems

Common Mistakes and How to Avoid Them

16.1 Misconceptions about d- and f-block Chemistry

16.2 Avoiding Calculation Errors in JEE Problems

Practice Problems with Detailed Solutions

17.1 Topic-wise Practice Problems (MCQs, Integer Type, Assertion-Reason)

17.2 Conceptual Questions (Application-Based, Reaction-Based)

17.3 Advanced Problems for JEE (Challenging Questions for Rank Boost)

PART 6: APPENDICES AND RESOURCES

18. Appendices

18.1 List of Important Reactions of d- and f-Block Elements

18.2 Tables of Oxidation States, Ionic Radii, and Electronegativity

18.3 Summary of Key Concepts and Formulae

Quick Revision Notes for JEE

19.1 One-Page Summaries of d- and f-Block Concepts

Mock Tests and Previous Year JEE Questions

20.1 Chapter-Wise JEE Main and Advanced Questions

20.2 Full-Length Practice Tests (JEE Level)

Solutions and Explanations for Practice Problems

Index

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