The Synthetic Use of Metals in Organic Chemistry (informative book)
Free download The Synthetic Use of Metals in Organic Chemistry
Authors of: The Synthetic Use of Metals in Organic Chemistry
Arthur J. Hale
Table of Contents in The Synthetic Use of Metals in Organic Chemistry
CHAPTER I.
SODIUM AND POTASSIUM.
Synthetic Use of the Metals—Sodium ethylate—Sodamide
—Sodium hydroxide—Potassium cyanide—Potassium
“bisulphate—Potassium hydroxide —Potassium nitrate
—Potassium and sodium disulphates
CHAPTER II.
COPPER AND SILVHXt.
Use of the Metals—Copper acetylene derivatives—Silver
cyanide—Silver hydroxide
CHAPTER III.
MAG-NESIUM, CALCIUM AND BARIUM.
Applications of the Grignard reagent—Carbides of Calcium
and Barium—Nitrogen fixation—Calcium and Magnesium nitrides—Hydroxides of the metals
CHAPTER IV.
ZINO AND MERCURY.
Metallic Zinc—Zinc chloride—Mercuric oxide—Metallic
mercury ^
CHAPTER V.
ALUMINIUM, TIN AND LEAD.
Aluminium chloride—Aluminium-mercury couple—Tin and
lead organo-metallie compounds—Tin tetrachloride—
Lead oxide—Antimony and the chlorides of antimony—
Vanadium pentoxidc
CHAPTER VI.
IRON, NICKEL AND PLATINUM.
Ferrous sulphate—Ferrous potassium oxalate—Iron and
ferric chloride—Reduction by reduced iron, nickel or cobalt
APPENDIX I.
PRACTICAL WORK: SODIUM—POTASSIUM.
Ethyl benzene—Anisole—Benzoic anhydride—Hexamethylene—Trimethylene dicarboxylic acid—Chlorof ormic
ester—Carbonyl chloride—• Ethyl benzoate—Toluic ethyl
ester—Aeetoacetic ester—Ethyl acetoacotic ethyl ester
—Aceto-succinic ester—Malonic ester—Ethyl malonic
ester—Diaceto-succinic ester—Ethane tetra-carboxylic
ester — Acetyl-acetoacetic ester—Antipy rine—Methyl
succinic ester—Succino-succinic ester—Tin tetraphenyl
—Lead tetraphenyl—Mercury diphenyl—Silicon tetraphenyl—Oxalyl-acetic ester—Hydroxy-methylene camphor—Acetyl-acetophenone—Ethyl acetophenone—Furfurol acrolein—Cinnamyl-vinyl-methyl ketone—Acetic
anhydride — Benzoin — Desyl-acetophenone — Phonanthroxylene-acetoacetic ester
APPENDIX II.
PRACTICAL WORK : COPP1R—SILVER.
Acrolein—Acrylic acid—/3-Iodopropionic acid—Adipi c acid
—Carbazole—o-Nitrophenyl-propiolic acid—Di-o-nitrophenyl-diacetylene — o-Chlor -toluene — o-Chlor-benzoio
acid—jp-Chlor-toluene—Formaldehyde
APPENDIX III.
PRACTICAL WORK: MAGNESIUM—CALCIUM.
Benzoic acid—Phenyl-ethyl-carbinol—Trimethyl carbinol—
Triphenyl carbinol—Camphoric anhydride—Homo-camphoric acid—Camphor—Pentamethylene—Cyanamide
APPENDIX IV.
PRACTICAL WORK : ZINC—MERCURY.
Citric acid—Use of Zinc alkyl iodide—Naphthalene—Isoquinoline—ITuorescein—Malachite green—Acridine—
a-Methyl-indole—Propyl chloride—a-Ethoxy-quinoline—Phthalic acid
APPENDIX V.
PRACTICAL WORK: ALUMINIUM—TIN—LEAD.
Dimethyl-aniline-phosphor-chloride — jp-Tolxiic-aldehyde —
Diphenyl-methane—a-Hydrindone—Triphenyl-methane—Acetophenone—o-Benzoyl-benzoic acid—Anthraquinone — Hydrolysis of anisole—Toluene—Diphenyl—
Oxalic acid
APPENDIX VI.
PRACTICAL WORK: IRON—NICKEL.
o-Amino-benzaldehyde—o-Amino-cinnamic acid—Mannose
—Hexahydrobenzene—Hexahydrophenol
INDEX
Title: In-Depth Exploration of Metal Reactions and Practical Applications in Organic Chemistry
Chapter I: Sodium and Potassium
The initial chapter delves into the synthetic utilization of sodium and potassium metals, covering various compounds such as sodium ethylate, sodamide, sodium hydroxide, potassium cyanide, potassium bisulphate, potassium hydroxide, potassium nitrate, and sodium and potassium disulphates.
Chapter II: Copper and Silver
This section explores the practical uses of copper and silver metals, encompassing copper acetylene derivatives, silver cyanide, and silver hydroxide.
Chapter III: Magnesium, Calcium, and Barium
The third chapter centers on applications of the Grignard reagent, emphasizing carbides of calcium and barium, nitrogen fixation, calcium and magnesium nitrides, and hydroxides of the metals.
Chapter IV: Zinc and Mercury
Examining metallic zinc, zinc chloride, mercuric oxide, and metallic mercury, this chapter provides insights into the diverse applications of zinc and mercury in chemical reactions.
Chapter V: Aluminium, Tin, and Lead
Aluminium chloride, aluminium-mercury couple, tin and lead organo-metallic compounds, tin tetrachloride, lead oxide, antimony, and the chlorides of antimony, along with vanadium pentoxide, are explored in this comprehensive chapter.
Chapter VI: Iron, Nickel, and Platinum
Focusing on iron, nickel, and platinum, this chapter investigates ferrous sulphate, ferrous potassium oxalate, iron and ferric chloride, and reduction processes using reduced iron, nickel, or cobalt.
Appendix I: Practical Work – Sodium and Potassium
Featuring practical applications, this appendix includes the synthesis of various compounds such as ethyl benzene, anisole, benzoic anhydride, hexamethylene, trimethylene dicarboxylic acid, chloroformic ester, carbonyl chloride, ethyl benzoate, toluic ethyl ester, acetoacetic ester, ethyl acetoacetic ethyl ester, aceto-succinic ester, malonic ester, ethyl malonic ester, diaceto-succinic ester, ethane tetra-carboxylic ester, acetyl-acetoacetic ester, antipyrine, methyl succinic ester, succino-succinic ester, tin tetraphenyl, lead tetraphenyl, mercury diphenyl, silicon tetraphenyl, oxalyl-acetic ester, hydroxy-methylene camphor, acetyl-acetophenone, ethyl acetophenone, furfuryl acrolein, cinnamyl-vinyl-methyl ketone, acetic anhydride, benzoin, desyl-acetophenone, and phananthroxylene-acetoacetic ester.
Appendix II: Practical Work – Copper and Silver
This section outlines practical applications involving copper and silver, covering acrolein, acrylic acid, beta-iodopropionic acid, adipic acid, carbazole, o-nitrophenyl-propiolic acid, di-o-nitrophenyl-diacetylene, o-chlor-toluene, o-chlor-benzoic acid, p-chlor-toluene, and formaldehyde.
Appendix III: Practical Work – Magnesium and Calcium
Detailed practical applications include the synthesis of benzoic acid, phenyl-ethyl-carbinol, trimethyl carbinol, triphenyl carbinol, camphoric anhydride, homo-camphoric acid, camphor, pentamethylene, and cyanamide.
Appendix IV: Practical Work – Zinc and Mercury
This appendix explores practical applications involving zinc and mercury, covering citric acid, the use of zinc alkyl iodide, naphthalene, isoquinoline, fluorescein, malachite green, acridine, alpha-methyl-indole, propyl chloride, alpha-ethoxy-quinoline, and phthalic acid.
Appendix V: Practical Work – Aluminium, Tin, and Lead
Providing practical insights into aluminum, tin, and lead, this section includes the synthesis of dimethyl-aniline-phosphor-chloride, p-toluic-aldehyde, diphenyl-methane, alpha-hydrindone, triphenyl-methane, acetophenone, o-benzoyl-benzoic acid, anthraquinone, hydrolysis of anisole, toluene, diphenyl, and oxalic acid.
Appendix VI: Practical Work – Iron and Nickel
The final appendix focuses on practical applications involving iron and nickel, covering o-amino-benzaldehyde, o-amino-cinnamic acid, mannose, hexahydrobenzene, and hexahydrophenol.
Index
An index is provided for easy reference to key concepts and compounds discussed throughout the book.
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