Free download Physical Chemistry By Robert J. Silbey 4th Edition

4th Edition

Authors of: Physical Chemistry By Robert J. Silbey 4th Edition

Robert J. Silbey

Robert A. Alberty

Moungi G. Bawendi

Table of Contents in Physical Chemistry By Robert J. Silbey 4th Edition

PART ONE

THERMODYNAMICS

Zeroth Law of Thermodynamics and Equations of State

Concept of thermal equilibrium and temperature

Definition and significance of the Zeroth Law

Equations of state for ideal and real gases

Van der Waals equation and compressibility factor

Thermodynamic surfaces and phase diagrams

First Law of Thermodynamics

Energy conservation and internal energy

Work, heat, and the concept of enthalpy

Heat capacities at constant volume and pressure

Applications of the First Law in closed and open systems

Thermochemistry: Hess’s Law and bond enthalpy calculations

Second and Third Laws of Thermodynamics

Entropy and spontaneous processes

Clausius inequality and the concept of reversibility

Free energy and equilibrium conditions

Absolute zero and the Third Law of Thermodynamics

Statistical interpretation of entropy

Fundamental Equations of Thermodynamics

Maxwell’s relations and their significance

Thermodynamic potentials and natural variables

Legendre transformations in thermodynamics

Stability criteria and phase transitions

Applications in physical and chemical systems

Chemical Equilibrium

Equilibrium constant and reaction direction

Relationship between Gibbs free energy and equilibrium

Le Chatelier’s principle and system responses

Temperature dependence of equilibrium constants

Applications in industrial and biochemical processes

Phase Equilibrium

Phase rule and classification of phase transitions

Clapeyron and Clausius-Clapeyron equations

Liquid-vapor, solid-liquid, and solid-solid equilibria

Phase diagrams of single and multicomponent systems

Supercritical fluids and their thermodynamic properties

Electrochemical Equilibrium

Electrochemical cells and Nernst equation

Standard electrode potentials and redox reactions

Batteries, fuel cells, and corrosion processes

Thermodynamic derivation of electrochemical properties

Applications in energy storage and industrial chemistry

Thermodynamics of Biochemical Reactions

Thermodynamic basis of bioenergetics

ATP hydrolysis and coupled reactions

Enzyme catalysis and Gibbs free energy in biological systems

Thermodynamic control of metabolic pathways

Applications in biotechnology and medicine

PART TWO

QUANTUM CHEMISTRY

Quantum Theory

Historical development of quantum mechanics

Wave-particle duality and Heisenberg’s uncertainty principle

Schrödinger equation and quantum states

Operators, eigenfunctions, and eigenvalues

Quantum mechanical postulates and interpretations

Atomic Structure

Quantum numbers and atomic orbitals

Electron configuration and periodic trends

Spin-orbit coupling and fine structure

Multi-electron atoms and electron correlation

Atomic spectra and selection rules

Molecular Electronic Structure

Molecular orbital theory and bonding

Valence bond theory and hybridization

Electronic structure of diatomic and polyatomic molecules

Huckel theory and aromaticity

Computational methods in molecular quantum chemistry

Symmetry

Symmetry elements and operations

Point groups and character tables

Applications of symmetry in spectroscopy

Molecular vibrations and group theory

Chemical bonding analysis using symmetry

Rotational and Vibrational Spectroscopy

Quantum mechanics of rotational motion

Selection rules and rotational spectra

Infrared and Raman spectroscopy

Normal modes of vibration in molecules

Applications in structural determination

Electronic Spectroscopy of Molecules

Absorption of light and molecular excitation

Electronic transitions and spectroscopic selection rules

Fluorescence and phosphorescence

Photoelectron spectroscopy and ionization energy

Applications in materials science and photophysics

Magnetic Resonance Spectroscopy

Principles of nuclear magnetic resonance (NMR)

Chemical shift and spin-spin coupling

Electron spin resonance (ESR) spectroscopy

Applications in structural and medical imaging

Advanced techniques: 2D-NMR and solid-state NMR

Statistical Mechanics

Boltzmann distribution and partition functions

Relationship between microscopic states and macroscopic properties

Statistical interpretation of entropy and free energy

Classical vs. quantum statistical mechanics

Applications in thermodynamics and spectroscopy

PART THREE

KINETICS

Kinetic Theory of Gases

Assumptions and derivation of kinetic theory

Maxwell-Boltzmann distribution and molecular speeds

Transport properties: diffusion, viscosity, and thermal conductivity

Collisions and mean free path in gases

Applications in atmospheric and astrophysical chemistry

Experimental Kinetics and Gas Reactions

Measurement of reaction rates

Rate laws and reaction order determination

Mechanisms of gas-phase reactions

Unimolecular and bimolecular reaction dynamics

Pressure and temperature dependence of reaction rates

Chemical Dynamics and Photochemistry

Transition state theory and activated complexes

Potential energy surfaces and reaction coordinates

Photochemical reactions and quantum yield

Energy transfer and photophysical processes

Applications in atmospheric chemistry and photosynthesis

Kinetics in the Liquid Phase

Diffusion-controlled and activation-controlled reactions

Solvent effects on reaction rates

Kinetics of catalyzed reactions

Electrochemical reaction kinetics

Applications in enzymatic and industrial processes

PART FOUR

MACROSCOPIC AND MICROSCOPIC STRUCTURES

Macromolecules

Structure and properties of polymers

Molecular weight determination and distributions

Polymerization kinetics and mechanisms

Thermodynamic and mechanical properties of macromolecules

Applications in materials science and biomaterials

Electric and Magnetic Properties of Molecules

Polarizability and dielectric properties

Magnetic susceptibility and molecular interactions

Optical activity and chiral molecules

Quantum mechanical treatment of molecular properties

Applications in spectroscopy and materials science

Solid-State Chemistry

Crystal structures and lattice dynamics

Band theory and electrical conductivity

Defects and non-stoichiometry in solids

Synthesis and characterization of solid materials

Applications in semiconductors and nanotechnology

Surface Dynamics

Adsorption isotherms and surface reactions

Catalysis and heterogeneous reaction mechanisms

Surface structure and spectroscopic techniques

Self-assembly and nanostructured materials

Applications in industrial and environmental chemistry

APPENDIX

Physical Quantities and Units

SI units and their conversions

Commonly used non-SI units in chemistry

Dimensional analysis and unit consistency

Values of Physical Constants

Fundamental constants in physics and chemistry

Atomic and molecular properties

Tables of Physical Chemical Data

Thermodynamic properties of substances

Spectroscopic and kinetic data

Mathematical Relations

Common equations in physical chemistry

Integral and differential calculus applications

Greek Alphabet

Symbols and their scientific usage

Useful Information on the Web

Online resources for chemistry research and learning

Symbols for Physical Quantities and Their SI Units

Standard notation in scientific literature

Answers to Selected Problems

INDEX

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