Physical Chemistry by Robert G. Mortimer Third Edition

Physical Chemistry by Robert G. Mortimer Third Edition

Physical Chemistry by Robert G. Mortimer Third Edition

Free Download Physical Chemistry by Robert G. Mortimer Third Edition

Physical Chemistry by Robert G. Mortimer Third Edition


Robert G. Mortimer

Professor Emeritus

Rhodes College

Memphis, Tennessee


Table of Contents


Periodic Table

Inside front cover

List of Numerical Tables in Appendix A

Inside front cover

Information Tables

Inside back cover

Preface xv

Acknowledgments xvii

Part 1 Thermodynamics and the Macroscopic

Description of Physical Systems 1

Chapter 1 The Behavior of Gases and Liquids 3

Chapter 2 Work, Heat, and Energy: The First Law of

Thermodynamics 39

Chapter 3 The Second and Third Laws of Thermodynamics:

Entropy 105

Chapter 4 The Thermodynamics of Real Systems 151

Chapter 5 Phase Equilibrium 199

Chapter 6 The Thermodynamics of Solutions 237

Chapter 7 Chemical Equilibrium 303

Chapter 8 The Thermodynamics of Electrochemical Systems 351

Part 2 Dynamics 381

Chapter 9 Gas Kinetic Theory: The Molecular Theory of Dilute Gases at

Equilibrium 383

Chapter 10 Transport Processes 441

Chapter 11 The Rates of Chemical Reactions 485

Chapter 12 Chemical Reaction Mechanisms I: Rate Laws and

Mechanisms 523

Chapter 13 Chemical Reaction Mechanisms II: Catalysis and Miscellaneous

Topics 565

Part 3 The Molecular Nature of Matter 617

Chapter 14 Classical Mechanics and the Old Quantum Theory 619

Chapter 15 The Principles of Quantum Mechanics. I. De BroglieWaves and

the Schrödinger Equation 653

Chapter 16 The Principles of Quantum Mechanics. II. The Postulates of

Quantum Mechanics 683

Chapter 17 The Electronic States of Atoms. I. The Hydrogen Atom 725

Chapter 18 The Electronic States of atoms. II.The Zero-OrderApproximation

for Multielectron Atoms 763

Chapter 19 The Electronic States of Atoms. III. Higher-Order

Approximations 789

Chapter 20 The Electronic States of Diatomic Molecules 823

Chapter 21 The Electronic Structure of Polyatomic Molecules 867

Chapter 22 Translational, Rotational, and Vibrational States of Atoms and

Molecules 915

Chapter 23 Optical Spectroscopy and Photochemistry 949

Chapter 24 Magnetic Resonance Spectroscopy 1001

Part 4 The Reconciliation of the Macroscopic and Molecular

Theories of Matter 1037

Chapter 25 Equilibrium Statistical Mechanics I. The Probability

Distribution for the Molecular States 1039

Chapter 26 Equilibrium Statistical Mechanics. II. Statistical

Thermodynamics 1081

Chapter 27 Equilibrium Statistical Mechanics. III. Ensembles 1121

Chapter 28 The Structure of Solids, Liquids, and Polymers 1153

Appendices 1209

Index 1351

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