Free download Organic Reaction Mechanism and Named Reactions for CSIR 2nd Edition

2nd Edition

Authors of:  Organic Reaction Mechanism and Named Reactions for CSIR 2nd Edition

Career Endeavor Publications

Table of Contents in Organic Reaction Mechanism and Named Reactions for CSIR 2nd Edition

Preface  

An introductory section discussing the purpose of the book, its relevance for CSIR exams, and how to approach organic reaction mechanisms effectively.

Chapter 1: Fundamentals of Organic Reaction Mechanisms

1.1 Introduction to Organic Reactions  

1.2 Types of Organic Reactions  

– Substitution  

– Addition  

– Elimination  

– Rearrangement  

1.3 Reactive Intermediates  

– Carbocations  

– Carbanions  

– Free Radicals  

– Carbenes  

1.4 Bond Breaking and Making  

1.5 Thermodynamics and Kinetics in Organic Reactions  

1.6 Mechanism Analysis  

1.7 Importance of Mechanisms in Exam Preparation

Chapter 2: Nucleophilic Substitution Reactions (SN1, SN2)

2.1 Introduction to Nucleophilic Substitution  

2.2 SN1 Reactions: Mechanism and Examples  

2.3 SN2 Reactions: Mechanism and Examples  

2.4 Factors Affecting SN1 and SN2 Reactions  

2.5 Rearrangements in SN1 Reactions  

2.6 Comparison of SN1 and SN2 Reactions  

2.7 Applications in Organic Synthesis  

Named Reactions in This Chapter:  

– Williamson Ether Synthesis  

– Finkelstein Reaction  

– Mitsunobu Reaction  

Chapter 3: Electrophilic Addition Reactions

3.1 General Mechanism of Electrophilic Addition  

3.2 Addition of Halogens and Hydrogen Halides  

3.3 Hydroboration-Oxidation Mechanism  

3.4 Oxymercuration-Demercuration  

3.5 Markovnikov and Anti-Markovnikov Additions  

3.6 Stereoselectivity in Electrophilic Additions  

3.7 Application in Synthetic Organic Chemistry  

Named Reactions in This Chapter:

– Markovnikov Addition  

– Anti-Markovnikov Addition  

– Simmons-Smith Reaction

Chapter 4: Elimination Reactions (E1, E2)  

4.1 Types of Elimination Reactions  

4.2 E1 Reaction Mechanism  

4.3 E2 Reaction Mechanism  

4.4 Factors Influencing Elimination Reactions  

4.5 Stereochemistry in Elimination Reactions  

4.6 Saytzeff and Hofmann Products  

Named Reactions in This Chapter:  

– Cope Elimination  

– Hofmann Elimination  

Chapter 5: Free Radical Reactions  

5.1 Introduction to Free Radicals  

5.2 Homolytic Bond Cleavage  

5.3 Types of Free Radical Reactions  

5.4 Halogenation of Alkanes  

5.5 Radical Polymerization  

5.6 Importance in Synthesis  

Named Reactions in This Chapter:  

– Wohl-Ziegler Reaction  

– Kolbe Electrolysis  

Chapter 6: Aromatic Substitution Reactions

6.1 Electrophilic Aromatic Substitution (EAS)  

6.2 Types of EAS Reactions  

6.3 Substituent Effects on Aromatic Rings  

6.4 Nucleophilic Aromatic Substitution (NAS)  

6.5 Mechanisms for NAS Reactions  

6.6 Applications in Synthesis  

Named Reactions in This Chapter:  

– Friedel-Crafts Alkylation and Acylation  

– Sandmeyer Reaction  

– Gattermann Reaction  

– Vilsmeier-Haack Reaction  

Chapter 7: Rearrangement Reactions

7.1 Introduction to Rearrangements  

7.2 Types of Rearrangement Mechanisms  

– Carbocation Rearrangements  

– Radical Rearrangements  

7.3 Applications of Rearrangements in Synthesis  

Named Reactions in This Chapter:  

– Wagner-Meerwein Rearrangement  

– Pinacol-Pinacolone Rearrangement  

– Beckmann Rearrangement  

– Baeyer-Villiger Oxidation  

Chapter 8: Oxidation and Reduction Reactions

8.1 Mechanism of Oxidation Reactions  

8.2 Common Oxidizing Agents  

8.3 Mechanism of Reduction Reactions  

8.4 Common Reducing Agents  

8.5 Selectivity in Oxidation and Reduction  

Named Reactions in This Chapter:

– Swern Oxidation  

– Wolff-Kishner Reduction  

– Clemmensen Reduction  

Chapter 9: Pericyclic Reactions

9.1 Introduction to Pericyclic Reactions  

9.2 Classification and Types  

9.3 Mechanism and Stereochemistry  

9.4 Electrocyclic Reactions  

9.5 Cycloaddition Reactions  

9.6 Sigmatropic Rearrangements  

Named Reactions in This Chapter:  

– Diels-Alder Reaction  

– Claisen Rearrangement  

– Cope Rearrangement  

Chapter 10: Heterocyclic Chemistry

10.1 Structure and Properties of Heterocycles  

10.2 Synthesis and Reactions of Five-membered Heterocycles  

10.3 Six-membered Heterocycles  

10.4 Fused Heterocycles  

10.5 Biological Importance and Applications  

Chapter 11: Organic Synthesis Strategies and Retrosynthesis

11.1 Introduction to Retrosynthesis  

11.2 Synthetic Planning and Strategies  

11.3 Common Synthetic Reactions in Planning  

11.4 Protecting Groups in Synthesis  

Named Reactions in This Chapter:  

– Robinson Annulation  

– Stork Enamine Synthesis  

Chapter 12: Advanced Mechanistic Topics for CSIR Preparation

12.1 Tips for CSIR Exam Preparation  

12.2 Mechanistic Practice Problems  

12.3 Analysis of Previous Exam Questions  

12.4 Advanced Problem-Solving Strategies  

Appendix

A. Summary of Named Reactions  

B. List of Common Reagents and Their Applications  

C. Reference Material for Advanced Study  

Index  

An alphabetical listing of topics, reactions, and named mechanisms to aid in quick reference for students preparing for the CSIR exam.  

File Size: 5.59 MB. Pages: 376 Please read Disclaimer.

Free download Organic Reaction Mechanism and Named Reactions for CSIR 2nd Edition

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