Atkins’ Physical Chemistry by Peter Atkins & Julio de Paula 8th Edition
Free Download Atkins’ Physical Chemistry by Peter Atkins & Julio de Paula 8th Edition
Atkins’ Physical Chemistry
Authors:
Peter Atkins
Professor of Chemistry,
University of Oxford, and Fellow of Lincoln College, Oxford
Julio de Paula
Professor and Dean of the College of Arts and Sciences
Lewis and Clark College, Portland, Oregon
Table of Contents
PART 1 Equilibrium
1 The properties of gases
The perfect gas
Real gases
2 The First Law
The basic concepts
Thermochemistry
State functions and exact differentials
3 The Second Law
The direction of spontaneous change
Concentrating on the system
Combining the First and Second Laws
4 Physical transformations of pure substances
Phase diagrams
Phase stability and phase transitions
5 Simple mixtures
The thermodynamic description of mixtures
The properties of solutions
Activities
6 Phase diagrams
Phases, components, and degrees of freedom
Two-component systems
7 Chemical equilibrium
Spontaneous chemical reactions
The response of equilibria to the conditions
Equilibrium electrochemistry
PART 2 Structure
Atkins’ Physical Chemistry
8 Quantum theory: introduction and principles
The origins of quantum mechanics
The dynamics of microscopic systems
Quantum mechanical principles
Translational motion
Vibrational motion
Rotational motion
Techniques of approximation
10 Atomic structure and atomic spectra
The structure and spectra of hydrogenic atoms
The structures of many-electron atoms
The spectra of complex atoms
11 Molecular structure
The Born–Oppenheimer approximation
Valence-bond theory
Molecular orbital theory
Molecular orbitals for polyatomic systems
12 Molecular symmetry
The symmetry elements of objects
Applications to molecular orbital theory and spectroscopy
General features of spectroscopy
Pure rotation spectra
The vibrations of diatomic molecules
The vibrations of polyatomic molecules
14 Molecular spectroscopy 2: electronic transitions
The characteristics of electronic transitions
The fates of electronically excited states
Lasers Atkins’ Physical Chemistry
15 Molecular spectroscopy 3: magnetic resonance
The effect of magnetic fields on electrons and nuclei
Nuclear magnetic resonance
Pulse techniques in NMR
Electron paramagnetic resonance
16 Statistical thermodynamics 1: the concepts
The distribution of molecular states
The internal energy and the entropy
The canonical partition function
17 Statistical thermodynamics 2: applications
Fundamental relations
Using statistical thermodynamics
18 Molecular interactions
Electric properties of molecules
Interactions between molecules
Gases and liquids
19 Materials 1: macromolecules and aggregates
Determination of size and shape
Structure and dynamics
Self-assembly
Crystal lattices
Crystal structure
The properties of solids
PART 3 Change
21 Molecules in motion
Molecular motion in gases
Molecular motion in liquids
Diffusion
22 The rates of chemical reactions
Empirical chemical kinetics
Accounting for the rate laws
23 The kinetics of complex reactions
Chain reactions
Polymerization kinetics
Homogeneous catalysis
Photochemistry
24 Molecular reaction dynamics
Reactive encounters
Transition state theory
The dynamics of molecular collisions
Electron transfer inhomogeneous systems
25 Processes on solid surfaces
The growth and structure of solid surfaces
The extent of adsorption
Heterogeneous catalysis
Processes at electrodes
Appendix 1 Quantities, units, and notational
Names of quantities
Units Atkins’ Physical Chemistry
Notational conventions
Appendix 2 Mathematical techniques
Basic procedures
Calculus
Statistics and probability
Matrix algebra
Appendix 3 Essential concepts of physics
Energy
Classical mechanics
Waves
Electrostatics
Data section
Answers to ‘b’ exercises
Answers to selected problems
Index
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