Thermodynamics Fundamentals for Applications By J. P. O’Connell (informative)
Free download Thermodynamics Fundamentals for Applications By J. P. O’Connell
Authors of: Thermodynamics Fundamentals for Applications By J. P. O’Connell
J P. O’Connell
J M. Haile
Table of Contents in Thermodynamics Fundamentals for Applications By J. P. O’Connell
Preface
Acknowledgments
0.Introduction
0.1 Natural Phenomena,
0.2 Thermodynamics, Science, and Engineering,
0.3 Why Thermodynamics Is Challenging,
0.4 The Role of Thermodynamic Modeling,
Literature Cited,
PART I.THE BASICS,
1.Primitives,
1.1 Primitive Things,
1.2 Primitive Quantities,
1.3 Primitive Changes,
1.4 Primitive Analyses,
1.5Summary,
Literature Cited,
Problems,
2.The First and Second Laws,
2.1 Work,
2.2 The First Law,
2.3 The Second Law,
2.4 Thermodynamic Stuff Equations,
2.5Summary,
Literature Cited,
Problems,
3.Fundamental Relations,
3.1 State of Single Homogeneous Phases,
3.2 Fundamental Equations,
3.3 Response to a Change in T, P, or V,
3.4 Response to a Change in Mole Number,
3.5Differential Relations Between Conceptuals and Measurables,
3.6 Generalized Stuff Equations,
3.7 General Expressions for Heat and Work,
3.8 Summary,
1.Primitives,
1.1 Primitive Things,
1.2 Primitive Quantities,
1.3 Primitive Changes,
1.4 Primitive Analyses,
1.5Summary,
Literature Cited,
Problems,
2.The First and Second Laws,
2.1 Work,
2.2 The First Law,
2.3 The Second Law,
2.4 Thermodynamic Stuff Equations,
2.5Summary,
Literature Cited,
Problems,
3.Fundamental Relations,
3.1 State of Single Homogeneous Phases,
3.2 Fundamental Equations,
3.3 Response to a Change in T, P, or V,
3.4 Response to a Change in Mole Number,
3.5Differential Relations Between Conceptuals and Measurables,
3.6 Generalized Stuff Equations,
3.7 General Expressions for Heat and Work,
3.8 Summary,
Literature Cited,
Problems,
PART II.SINGLE-PHASE SYSTEMS,
4.Properties Relative to Ideal Gases,
4.1 Ideal Gases,
4.2 Deviations from Ideal Gases: Difference Measures,
4.3 Deviations from Ideal Gases: Ratio Measures,
4.4 Conceptuals from Measurables Using Equations of State,
4.5Simple Models for Equations of State,
4.6 Summary,
Literature Cited,
Problems,
5.Properties Relative to Ideal Solutions,
5.1 Ideal Solutions,
5.2 Deviations from Ideal Solutions: Difference Measures,
5.3 Excess Properties from Residual Properties,
5.4 Deviations from Ideal Solutions: Ratio Measures,
5.5 Activity Coefficients from Fugacity Coefficients,
5.6 Simple Models for Nonideal Solutions,
5.7 Summary,
Literature Cited,
Problems,
6.Relations Among Relations,
6.1 Effects of External Constraints on System States,
6.2 Symmetry in Routes to Conceptuals,
6.3 Physical Interpretations of Selected Conceptuals,
6.4 Five Famous Fugacity Formulae,
6.5Mixing Rules from Models for Excess Gibbs Energy,
6.6 Summary,
Literature Cited,
Problems
PART III.MULTIPHASE AND REACTING SYSTEMS, 255
7.Transfers, Transformations, and Equilibria,
7.1 The Laws for Closed Nonreacting Systems,
7.2 The Laws for Open Nonreacting Systems,
7.3 Criteria for Phase Equilibrium,
7.4 The Laws for Closed Reacting Systems,
7.5The Laws for Open Reacting Systems,
7.6 Criteria for Reaction Equilibrium,
7.7 Summary,
Literature Cited,
Problems,
8.Criteria for Observability,
8.1 Phase Stability in Closed Systems,
8.2 Pure Substances,
8.3 Phase Stability in Open Systems,
8.4 Fluid Mixtures,
8.5Summary,
Literature Cited,
Problems,
9.Phase Diagrams for Real Systems,
9.1 Thermodynamic State for Multiphase Systems,
9.2 Pure Substances,
9.3 Binary Mixtures of Fluids at Low Pressures,
9.4 Binary Mixtures Containing Solids,
9.5Binary Mixtures of Fluids at High Pressures,
9.6 Ternary Mixtures,
9.7 Summary,
Literature Cited,
Problems,
PART IV.ENGINEERING CALCULATIONS,
10.Options for Equilibrium Calculations,
10.1 Basic Phase-Equilibrium Relations,
10.2 Choices for Standard States in Gamma Methods,
10.3 Basic Reaction-Equilibrium Relations,
10.4 Preliminaries to Reaction-Equilibrium Calculations,
10.5Choosing an Appropriate Form in Applications,
Literature Cited,
Problems,
11.Elementary Computational Procedures,
11.1 Phase-Equilibrium Calculations,
11.2 One-Phase Reaction-Equilibrium Calculations,
11.3 Multiphase Reaction-Equilibrium Calculations,
11.4 Summary,
Literature Cited,
Problems,
12.Selected Applications,
12.1 Phase Equilibria,
12.2 Solubilities,
12.3 Independent Variables in Steady-Flow Processes,
12.4 Heat Effects in Steady-Flow Processes,
12.5Response of Selected Properties,
12.6 Summary,
Literature Cited,
Problems,
AFTERWORD,
APPENDICES,
A. Tools from the Calculus,
B. Elements of Linear Algebra,
C. Solutions to Cubic Equations,
D. Vapor Pressures of Selected Fluids,
E. Parameters in Models for G Excess,
F. A Stability Condition for Binaries,
G. Notation in Variational Calculus,
H. Triangular Diagrams
I. Lagrange Multipliers
J. NRTL Model
K. Simple Algorithms for Binary VLLE
Notation
Index
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