Free download Organic Chemistry by Paula Yurkanis Bruice 8th Edition

8th Edition

Authors of:  Organic Chemistry by Paula Yurkanis Bruice 8th Edition

Paula Yurkanis Bruice

Table of Contents in Organic Chemistry by Paula Yurkanis Bruice 8th Edition

Preface

Chapter 1: Revisiting General Chemistry: Electronic Structure and Bonding

In this chapter, we delve into the fundamental principles of general chemistry that form the backbone of organic chemistry. It covers the basics of atomic structure, the arrangement of electrons within atoms, and how this influences bonding between atoms. You’ll revisit the concept of electronic configurations and learn how atomic orbitals combine to form chemical bonds, including covalent, ionic, and polar bonds. This chapter emphasizes the importance of understanding these basic principles to fully grasp more advanced organic chemistry topics.

Chapter 2: Acids and Bases: The Core of Organic Chemistry

This chapter introduces the pivotal role of acids and bases in organic chemistry. Understanding the behavior of acids and bases is essential for predicting chemical reactions, understanding reaction mechanisms, and making sense of organic reactivity. The chapter explains the Brønsted-Lowry and Lewis definitions of acids and bases, how to evaluate their strength, and the role of conjugate acids and bases. You’ll also learn how to calculate and interpret pKa values, a key concept in determining the acidity or basicity of various organic compounds.

Tutorial: Acids and Bases

A comprehensive tutorial on acids and bases follows Chapter 2. This section provides additional exercises and examples to solidify your understanding of the concepts introduced earlier. It’s designed to help you apply your knowledge to different scenarios and ensure a strong grasp of the material.

Chapter 3: Introduction to Organic Compounds

In this chapter, we begin to explore organic compounds in detail. You’ll be introduced to the wide variety of organic molecules and learn how to classify them based on functional groups, which are key determinants of their chemical behavior. The chapter covers the naming conventions of organic molecules (nomenclature), the structure of hydrocarbons, and the importance of isomerism. This foundational knowledge will set the stage for deeper exploration of organic reactions and mechanisms in subsequent chapters.

This overview gives a clear structure for students to follow, with each chapter building on the last to deepen understanding of organic chemistry.

Nomenclature, Physical Properties, and Structure  

TUTORIAL Using Molecular Models  

CHAPTER 4 Isomers: The Arrangement of Atoms in Space  

TUTORIAL Interconverting Structural Representations  

CHAPTER 5 Alkenes: Structure, Nomenclature, and an Introduction to Reactivity

Thermodynamics and Kinetics  

TUTORIAL Drawing Curved Arrows  

CHAPTER 6 The Reactions of Alkenes  

The Stereochemistry of Addition Reactions  

CHAPTER 7 The Reactions of Alkynes  

An Introduction to Multistep Synthesis  

CHAPTER 8 Delocalized Electrons: Their Effect on Stability, pKa, and the

Products of a Reaction

Aromaticity and Electronic Effects:

An Introduction to the Reactions of Benzene  

TUTORIAL Drawing Resonance Contributors  

CHAPTER 9 Substitution and Elimination Reactions of Alkyl Halides  

CHAPTER 10 Reactions of Alcohols, Ethers, Epoxides, Amines, and

Sulfur-Containing Compounds  

CHAPTER 11 Organometallic Compounds  

CHAPTER 12 Radicals  

TUTORIAL Drawing Curved Arrows in Radical Systems  

CHAPTER 13 Mass Spectrometry; Infrared Spectroscopy;

UV/Vis Spectroscopy  

CHAPTER 14 NMR Spectroscopy  

CHAPTER 15 Reactions of Carboxylic Acids and Carboxylic Acid Derivatives  

CHAPTER 16 Reactions of Aldehydes and Ketones  

More Reactions of Carboxylic Acid Derivatives  

CHAPTER 17 Reactions at the a-Carbon  

TUTORIAL Synthesis and Retrosynthetic Analysis  

CHAPTER 18 Reactions of Benzene and Substituted Benzenes  

CHAPTER 19 More About Amines • Reactions of Heterocyclic Compounds  

CHAPTER 20 The Organic Chemistry of Carbohydrates  

CHAPTER 21 Amino Acids, Peptides, and Proteins  

CHAPTER 22 Catalysis in Organic Reactions and in Enzymatic Reactions  

CHAPTER 23 The Organic Chemistry of the Coenzymes, Compounds Derived

from Vitamins  

CHAPTER 24 The Organic Chemistry of the Metabolic Pathways  

CHAPTER 25 The Organic Chemistry of Lipids  

CHAPTER 26 The Chemistry of the Nucleic Acids  

CHAPTER 27 Synthetic Polymers  

CHAPTER 28 Pericyclic Reactions  

APPENDICES I pKa Values A-1

II Kinetics A-3

III Summary of Methods Used to Synthesize a Particular

Functional Group A-8

IV Summary of Methods Employed to Form Carbon–Carbon

Bonds A-11

V Spectroscopy Tables A-12

VI Physical Properties of Organic Compounds A-18

VII Answers to Selected Problems ANS-1

Glossary G-1

Photo Credits C-1

Index

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Free download Organic Chemistry by Paula Yurkanis Bruice 8th Edition

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