Free download Inorganic Chemistry By Gary L. Miessler 3rd Edition

3rd Edition

Authors of: Inorganic Chemistry By Gary L. Miessler 3rd Edition

Gary L. Miessler

Table of Contents in Inorganic Chemistry By Gary L. Miessler 3rd Edition

1.1 Introduction to Inorganic Chemistry

1.2 Comparison with Organic Chemistry

1.3 Historical Background of Inorganic Chemistry

1.4 Overview and Perspectives

General References

Chapter 2: Atomic Structure

2.1 Development of Atomic Theory

2.1.1 The Periodic Table

2.1.2 Discovery of Subatomic Particles and the Bohr Model

2.2 The Schrödinger Equation

2.2.1 Particle in a Box Model

2.2.2 Quantum Numbers and Atomic Wave Functions

2.2.3 The Aufbau Principle

2.2.4 Electron Shielding

2.3 Periodic Trends in Atomic Properties

2.3.1 Ionization Energy

2.3.2 Electron Affinity

2.3.3 Covalent and Ionic Radii

General References • Problems

Chapter 3: Basic Bonding Theories

3.1 Lewis Structures

3.1.1 Resonance Structures

3.1.2 Expanded Octets

3.1.3 Formal Charge Calculations

3.1.4 Multiple Bonds in Beryllium and Boron Compounds

3.2 VSEPR Theory (Valence Shell Electron-Pair Repulsion)

3.2.1 Effects of Lone-Pair Repulsion

3.2.2 Influence of Multiple Bonds

3.2.3 Role of Electronegativity and Atomic Size

3.2.4 Ligand Packing Considerations

3.3 Molecular Polarity

3.4 Hydrogen Bonding

General References • Problems

Chapter 4: Symmetry and Group Theory

4.1 Symmetry Elements and Operations

4.2 Point Group Classification

4.2.1 High- and Low-Symmetry Groups

4.2.2 Additional Point Groups

4.3 Group Properties and Representations

4.3.1 Matrix Representations

4.3.2 Point Group Representations

4.3.3 Character Tables

4.4 Practical Applications of Symmetry

4.4.1 Chirality and Optical Activity

4.4.2 Molecular Vibrations

General References • Problems

Chapter 5: Molecular Orbitals

5.1 Formation from Atomic Orbitals

5.1.1 s Orbital Interactions

5.1.2 p Orbital Interactions

5.1.3 d Orbital Interactions

5.1.4 Nonbonding Orbitals and Additional Factors

5.2 Homonuclear Diatomic Molecules

5.2.1 Molecular Orbital Diagrams

5.2.2 Orbital Mixing Effects

5.2.3 Diatomic Molecules in Periods 1 and 2

5.2.4 Photoelectron Spectroscopy Insights

5.3 Heteronuclear Diatomic Molecules

5.3.1 Polar Bonds and Molecular Orbitals

5.3.2 Ionic Compounds and Molecular Orbitals

5.4 Molecular Orbitals in Larger Molecules

5.4.1 Example: FHF–

5.4.2 Example: CO₂

5.4.3 Example: H₂O

5.4.4 Example: NH₃

5.4.5 Revisiting CO₂ with Projection Operators

5.4.6 Example: BF₃

5.4.7 Hybrid Orbital Theory

General References • Problems

Chapter 6: Acid-Base and Donor-Acceptor Chemistry

6.1 Acid-Base Models and Concepts

6.1.1 Historical Development of Acid-Base Theories

6.2 Arrhenius Acid-Base Model

6.3 Brønsted-Lowry Acid-Base Theory

6.3.1 Acid-Base Behavior in Non-Aqueous Solvents

6.3.2 Superacids within the Brønsted-Lowry Framework

6.3.3 Thermodynamic Measurements in Solutions

6.3.4 Gas Phase Acidity and Basicity

6.3.5 Superbases in Brønsted-Lowry Theory

6.3.6 Trends in Basicity

6.3.7 Acid Strength of Binary Hydrogen Compounds

6.3.8 Strength of Oxyacids

6.3.9 Acidity of Aqueous Metal Cations

6.4 Lewis Acid-Base Theory and Frontier Orbitals

6.4.1 Acid-Base Reactions and Frontier Orbitals

6.4.2 Spectroscopic Evidence for Frontier Orbital Interactions

6.4.3 Quantifying Lewis Basicity

6.4.4 BF₃ Affinity Scale

6.4.5 Halogen Bonding Interactions

6.4.6 Inductive Effects on Lewis Acidity and Basicity

6.4.7 Steric Effects on Lewis Acidity and Basicity

6.4.8 Frustrated Lewis Pairs

6.5 Intermolecular Forces

6.5.1 Hydrogen Bonding Mechanisms

6.5.2 Host-Guest Interactions

6.6 Hard and Soft Acid-Base (HSAB) Theory

6.6.1 Theoretical Foundations of HSAB

6.6.2 Quantitative Aspects of HSAB Theory

General References • Problems

Chapter 7: Solid-State Chemistry

Chapter 8: Main Group Element Chemistry

8.1 Trends and Patterns in Main Group Elements

Chapter 9: Coordination Chemistry I — Structures and Isomerism

This chapter delves into the fundamental aspects of coordination chemistry, focusing on the structural diversity and isomerism exhibited by coordination complexes. Coordination chemistry explores the interactions between metal centers and surrounding ligands, forming coordination compounds that play essential roles in various chemical and biological systems. The unique spatial arrangements and connectivity patterns of these compounds contribute significantly to their physical, chemical, and biological properties

Chapter 10: Coordination Chemistry II — Bonding Theories

Chapter 11: Coordination Chemistry III — Electronic Spectroscopy

Chapter 12: Coordination Chemistry IV — Reaction Mechanisms

Chapter 13: Organometallic Chemistry

Chapter 14: Organometallic Reactions and Catalysis

Chapter 15: Comparisons Between Main Group and Organometallic Chemistry

Appendix A: Solutions to Exercises

Appendix B: Reference Data

Appendix C: Character Tables

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