A Textbook of Physical Chemistry By K L Kapoor 4th Edition Vol 4 (informative)
Free download A Textbook of Physical Chemistry By K L Kapoor 4th Edition Vol 4
Quantum chemistry and molecular spectroscopy
4th Edition
Vol 4
Authors of: A Textbook of Physical Chemistry By K L Kapoor 4th Edition Vol 4
K L Kapoor
Table of Contents in A Textbook of Physical Chemistry By K L Kapoor 4th Edition Vol 4
Chapter 1: Thermodynamics of Phase Equilibria
– 1.1 Introduction to Phase Equilibria
– Basic principles of phase equilibria
– Definitions: phases, components, and degrees of freedom
– 1.2 The Phase Rule
– Derivation and applications of the Gibbs Phase Rule
– Examples and exercises on phase rule application
– 1.3 Phase Diagrams
– One-component systems: water and sulfur systems
– Binary systems: phase diagrams for miscible and immiscible substances
– 1.4 Thermodynamics of Multicomponent Systems
– Gibbs free energy in multi-component systems
– Chemical potential and its role in phase equilibria
Chapter 2: Solutions and Colligative Properties
– 2.1 Solutions and Their Types
– Properties of solutions, solubility, and concentration units
– Ideal and non-ideal solutions
– 2.2 Raoult’s Law and Deviations
– Concept of ideality in solutions
– Positive and negative deviations from Raoult’s Law
– 2.3 Colligative Properties
– Freezing point depression, boiling point elevation, and osmotic pressure
– Calculations involving colligative properties
– 2.4 Van’t Hoff Factor and Abnormal Molar Masses
– Introduction to the van’t Hoff factor
– Effects of ionization and association on colligative properties
Chapter 3: Electrochemistry
– 3.1 Introduction to Electrochemical Cells
– Types of cells: Galvanic and electrolytic
– Cell notation and conventions
– 3.2 Electrode Potentials and EMF
– Standard electrode potential and its measurement
– Nernst equation and its applications
– 3.3 Thermodynamics of Electrochemical Cells
– Relationship between cell potential, free energy, and equilibrium constants
– 3.4 Conductance of Electrolytic Solutions
– Electrical conductance, molar conductance, and their measurements
– Kohlrausch’s Law and its applications
Chapter 4: Chemical Kinetics
– 4.1 Basic Concepts in Kinetics
– Reaction rates, rate laws, and the rate constant
– Order and molecularity of reactions
– 4.2 Kinetic Theories and Rate Laws
– The collision theory of reaction rates
– Transition state theory
– 4.3 Complex Reactions and Mechanisms
– Consecutive, parallel, and chain reactions
– Steady-state approximation and rate-determining step
– 4.4 Experimental Methods of Kinetic Study
– Techniques for measuring reaction rates
– Temperature dependence of reaction rates
Chapter 5: Surface Chemistry and Catalysis
– 5.1 Adsorption Phenomena
– Types of adsorption: physical and chemical
– Adsorption isotherms: Langmuir and Freundlich models
– 5.2 Surface Area and Surface Energy
– Surface area measurement techniques
– Surface tension and its applications
– 5.3 Catalysis and Reaction Mechanisms
– Role of catalysts in chemical reactions
– Enzyme catalysis and Michaelis-Menten kinetics
– 5.4 Colloidal State
– Properties of colloidal systems and preparation methods
– Coagulation, stability, and applications of colloids
Chapter 6: Quantum Chemistry and Molecular Spectroscopy
– 6.1 Fundamentals of Quantum Mechanics
– Postulates of quantum mechanics and Schrödinger’s equation
– Particle in a box and quantum tunneling concepts
– 6.2 Quantum Mechanics of Atoms and Molecules
– Atomic orbitals and electron configurations
– Molecular orbital theory and bonding
– 6.3 Molecular Spectroscopy
– Types of spectroscopy: UV-Vis, IR, and NMR
– Principles of electronic, vibrational, and rotational spectroscopy
– 6.4 Applications of Spectroscopy in Chemical Analysis
– Techniques and applications of spectroscopic methods
– Structure determination using spectroscopy
Chapter 7: Statistical Thermodynamics
– 7.1 Introduction to Statistical Thermodynamics
– Statistical interpretation of entropy
– Boltzmann distribution law
– 7.2 Partition Functions and Thermodynamic Quantities
– Translational, rotational, and vibrational partition functions
– Relationship between partition functions and thermodynamic properties
– 7.3 Applications to Chemical Systems
– Calculation of entropy, enthalpy, and free energy from partition functions
– Statistical mechanics of gases, solids, and liquids
– 7.4 Quantum Statistics and Ideal Gases
– Bose-Einstein and Fermi-Dirac statistics
– Applications to ideal gases and blackbody radiation
Chapter 8: Macromolecules and Polymer Chemistry
– 8.1 Basics of Polymer Chemistry
– Classification and types of polymers
– Polymerization mechanisms: addition and condensation
– 8.2 Molecular Weights of Polymers
– Number-average and weight-average molecular weights
– Techniques for molecular weight determination
– 8.3 Thermodynamics of Polymer Solutions
– Solubility parameters and Flory-Huggins theory
– Phase behavior of polymer solutions
– 8.4 Physical Properties of Polymers
– Crystallinity, glass transition temperature, and elasticity
– Mechanical and thermal properties of polymers
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