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Chemistry- Quantum Mechanics and Spectroscopy I by J. E. Parker

Chemistry- Quantum Mechanics and Spectroscopy I by J. E. Parker

Chemistry- Quantum Mechanics and Spectroscopy I by J. E. Parker

Free Download Chemistry- Quantum Mechanics and Spectroscopy I by J. E. Parker

Chemistry- Quantum Mechanics and Spectroscopy I by J. E. Parker

Authors:
J. E. Parker

 

Table of Contents

Acknowledgments 7

1 Quantum Mechanics 8

1.1 The Failures of Classical Mechanics 9

1.2 Wave-Particle Duality of Light 16

1.3 The Bohr Model for the Hydrogen Atom 18

1.4 The Wave-Particle Duality of Matter, the de Broglie Equation 20

1.5 Heisenbergs Uncertainty Principles 22

1.6 Physical Meaning of the Wavefunction of a Particle 24

1.7 Schrodinger’s Wave Equation 26

1.8 Comparison of Matter and Light 43

1.9 Spectroscopy and Specific Selection Rules 44

2 Pure Rotational Spectroscopy 47

2.1 Rigid Rotor Model for a Diatomic Molecule 48

2.2 Specific Selection Rule for Pure Rotational Spectroscopy 54

2.3 Gross Section Rule for Pure Rotational Spectroscopy 57

2.4 Rotational Motion of Polyatomic Molecules 58

2.5 Intensities of Rotational Lines 59

3 Pure Vibrational Spectroscopy 62

3.1 Simple Harmonic Oscillator (SHO) Model for a Vibrating Bond 63

3.2 Anharmonic Model for a Vibrating Molecule 68

3.3 Hot Band Transitions 71

3.4 Vibrational Spectra of Polyatomic Molecules 73

4 Vibration-Rotation Spectroscopy 78

4.1 Selection Rules for Vibration-Rotation Transitions 79

4.2 Rotations and Nuclear Statistics 83

5 Raman Spectroscopy 89

5.1 Rotational Raman Scattering 93

5.2 Vibrational Raman Scattering 95

5.3 Advantages and Applications of Raman Scattering 96

6 Atomic Spectroscopy 98

6.1 Analytical Applications of Atomic Spectroscopy 99

6.2 Atomic Quantum Numbers 100

6.3 Term Symbols, Selection Rules, and Spectra of Atoms 105

6.4 Hund’s Rules for Finding the Lower Energy Terms 111

7 Electronic Spectra 113

7.1 Term Symbols and Selection Rules for Diatomic Molecules 115

7.2 Vibrational Progressions 124

7.3 Electronic Spectra of Polyatomic Molecules 139

7.4 Decay of Electronically Excited Molecules 141

7.5 Ultraviolet Photoelectron Spectroscopy of Molecules 149

8 References 153

9 List of Formulae 154

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