Physical Chemistry Thermodynamics and Chemical Equilibrium By K L Kapoor Vol. 2 5th Edition (informative)
Free download Physical Chemistry Thermodynamics and Chemical Equilibrium By K L Kapoor Vol. 2 5th Edition
Volume 2
5th Edition
Authors of: Physical Chemistry Thermodynamics and Chemical Equilibrium By K L Kapoor Vol. 2 5th Edition
K L Kapoor
Table of Contents in Physical Chemistry Thermodynamics and Chemical Equilibrium By K L Kapoor Vol. 2 5th Edition
The “Physical Chemistry: Thermodynamics and Chemical Equilibrium” by K.L. Kapoor, Vol. 2, 5th Edition, provides a solid foundation for students exploring the principles of physical chemistry. This volume delves into the core concepts that form the basis of chemistry, physics, and materials science, offering detailed explanations of thermodynamics, chemical kinetics, electrochemistry, and the behavior of gases. The book is particularly designed to assist undergraduate students and those preparing for competitive exams, focusing on clarity of concepts and problem-solving techniques.
Starting with an introduction to the fundamentals of physical chemistry, the book gradually moves into more complex topics, including gas behavior, the laws of thermodynamics, phase equilibria, and chemical equilibrium. Kapoor’s writing style effectively blends theoretical knowledge with practical examples, making it easier for students to understand and appreciate the relevance of each concept. Additionally, the book is filled with solved examples, exercises, and illustrations to enhance understanding.
Moreover, the text emphasizes a methodical approach to solving numerical problems, helping students develop both conceptual understanding and analytical abilities. With its clear language and well-organized content, the book is an invaluable resource for mastering the intricate topics of physical chemistry in a systematic and logical way.
1. Introduction to Physical Chemistry
– Definition and scope of physical chemistry
– Basic concepts: matter, energy, and thermodynamics
2. Gaseous State
– Ideal gases and the ideal gas law
– Real gases: deviations from ideality
– Van der Waals equation and critical phenomena
– Kinetic theory of gases
– Maxwell-Boltzmann distribution
3. Thermodynamics
– First Law of Thermodynamics: internal energy, heat, and work
– Enthalpy, heat capacities, and thermochemistry
– Second Law of Thermodynamics: entropy and spontaneity
– Gibbs and Helmholtz free energy
– Criteria for equilibrium and spontaneity
– Third Law of Thermodynamics
4. Thermochemistry
– Standard enthalpy changes
– Hess’s law and bond enthalpy
– Calorimetry and heat measurements
5. Chemical Equilibrium
– Law of mass action and equilibrium constants
– Le Chatelier’s principle
– Temperature dependence of equilibrium constants
– Phase equilibria and the phase rule
Solutions and Colligative Properties
– Types of solutions and concentration units
– Raoult’s law and ideal solutions
– Non-ideal solutions and activity coefficients
– Colligative properties: lowering of vapor pressure, elevation of boiling point, depression of freezing point, and osmotic pressure
7. Electrochemistry
– Electrochemical cells and cell potentials
– Nernst equation
– Standard electrode potentials and electrochemical series
– Electrolysis and Faraday’s laws
– Conductance of electrolytic solutions
Chemical Kinetics
– Rate of reaction and rate laws
– Order and molecularity of reactions
– Integrated rate equations for different orders
– Theories of reaction rates: collision theory and transition state theory
– Catalysis and enzyme kinetics
9. Surface Chemistry
– Adsorption and adsorption isotherms
– Catalysis at surfaces
– Colloidal systems and properties
– Emulsions and gels
10. Quantum Chemistry
– Origins of quantum theory: Planck’s hypothesis and the photoelectric effect
– Wave-particle duality and de Broglie’s hypothesis
– Schrödinger’s equation and its applications
– Quantum mechanical model of the hydrogen atom
– Quantum numbers and atomic orbitals
11. Statistical Thermodynamics
– The concept of microstates and macrostates
– Boltzmann distribution law
– Partition function and its significance
– Applications of statistical thermodynamics
12. Spectroscopy
– Interaction of radiation with matter
– Basic principles of molecular spectroscopy
– Rotational, vibrational, and electronic spectra
– NMR and ESR spectroscopy
Molecular Structure and Bonding
– Valence bond theory (VBT) and molecular orbital theory (MOT)
– Hybridization and molecular shapes
– Bonding in diatomic molecules
– Intermolecular forces
Appendices
– Mathematical concepts for physical chemistry
– Important constants and conversion factors
– Glossary of terms
– Index
This outline is typical of the topics covered in physical chemistry textbooks and should be helpful in understanding the scope of Volume 1. You might want to refer to your specific edition for the exact chapter titles and content.
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Free download Physical Chemistry Thermodynamics and Chemical Equilibrium By K L Kapoor Vol. 2 5th Edition
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