Inorganic Chemistry 5th Edition by Shriver & Atkins’ (informative)
Free download Inorganic Chemistry 5th Edition by Shriver & Atkins’
5th Edition
Authors of: Inorganic Chemistry 5th Edition by Shriver & Atkins’
Shriver & Atkins’
Peter Atkins
Tina Overton
Jonathan Rourke
Mark Weller
Fraser Armstrong
Micheal Hagerman
Table of Contents in Inorganic Chemistry 5th Edition by Shriver & Atkins’
Part 1: Foundations
The first part of this book, titled “Foundations,” lays the groundwork for understanding the essential principles of inorganic chemistry. It begins by delving into the fundamental concepts that form the basis for more advanced discussions of chemical elements and compounds.
Chapter 1: Atomic Structure
The first chapter introduces the concept of atomic structure, providing a detailed explanation of the arrangement and behavior of subatomic particles, including protons, neutrons, and electrons. This chapter covers the historical development of atomic models, from early theories to modern quantum mechanical descriptions. It highlights key concepts such as orbitals, electron configurations, and the periodic nature of atomic properties. Understanding atomic structure is crucial for comprehending how atoms interact to form molecules and compounds, which sets the stage for subsequent chapters on bonding and molecular structure.
Chapter 2: Molecular Structure and Bonding
Chapter 2 explores the principles of molecular structure and bonding. The focus here is on how atoms bond to form molecules through ionic, covalent, and metallic bonds. The chapter introduces theories such as Valence Shell Electron Pair Repulsion (VSEPR) theory and Molecular Orbital theory to explain molecular shapes, bond energies, and hybridization. These fundamental bonding concepts are essential for understanding the behavior of molecules and their chemical reactions.
Chapter 3: The Structures of Simple Solids
In Chapter 3, attention shifts to the structures of simple solids, such as ionic, covalent, and metallic crystals. The chapter discusses lattice structures, coordination numbers, and the forces holding solids together. By examining examples of common solid-state materials, the reader will gain insight into the properties of materials and how their structures determine hardness, conductivity, and melting points.
Chapter 4: Acids and Bases
Chapter 4 introduces the chemistry of acids and bases, exploring various definitions, including the Brønsted-Lowry and Lewis theories. It discusses the concept of pH, acid and base strength, and the behavior of acids and bases in aqueous solutions. This chapter provides the foundation for understanding many reactions and equilibria that are central to both organic and inorganic chemistry.
Chapter 5: Oxidation and Reduction
Chapter 5 focuses on oxidation-reduction (redox) reactions, a class of reactions involving the transfer of electrons. This chapter explains how to determine oxidation states, balance redox reactions, and understand electrochemical processes. Redox chemistry is fundamental to understanding energy transfer in chemical systems, including batteries, corrosion, and biological processes.
Chapter 6: Molecular Symmetry
Molecular symmetry, the focus of Chapter 6, plays a vital role in determining the physical and chemical properties of molecules. Symmetry elements and operations, point groups, and their applications in spectroscopy are discussed. Understanding molecular symmetry is key to predicting molecular vibrations, optical activity, and chemical reactivity.
**Chapter 7: Introduction to Coordination Compounds**
In Chapter 7, the reader is introduced to coordination compounds, where transition metals are bonded to ligands. This chapter provides an overview of coordination chemistry, including concepts like coordination numbers, geometries, and ligand types. It also touches on the electronic and magnetic properties of coordination complexes, which are important for understanding their roles in catalysis and biological systems.
**Chapter 8: Physical Techniques in Inorganic Chemistry**
The final chapter of Part 1 focuses on the physical techniques used in inorganic chemistry to study molecular structures and properties. This includes techniques such as X-ray crystallography, nuclear magnetic resonance (NMR) spectroscopy, and infrared (IR) spectroscopy. The chapter provides an introduction to these methods, emphasizing how they are used to gather information about the composition, structure, and dynamics of inorganic compounds.
**Part 2: The Elements and Their Compounds**
The second part of the book shifts focus to a detailed exploration of the elements of the periodic table and their compounds. Each group of elements is covered, discussing their unique properties, reactivity, and applications.
**Chapter 9: Periodic Trends**
Chapter 9 begins by examining periodic trends across the elements, such as atomic size, ionization energy, electronegativity, and electron affinity. These trends help explain the chemical behavior of elements as one moves across or down the periodic table.
**Chapters 10 to 18: Hydrogen and the Main Group Elements**
Chapters 10 through 18 cover hydrogen and the main group elements, starting with hydrogen (Chapter 10), and moving through the elements of Groups 1 to 18. For each group, the chapters discuss the key characteristics of the elements, their common compounds, and their industrial and biological importance. These chapters also delve into the chemistry of alkali metals, alkaline earth metals, and the p-block elements, offering insights into their reactivity, bonding, and uses.
**Chapter 19: The d-Block Elements**
Chapter 19 shifts focus to the transition metals, or d-block elements, which are known for their complex chemistry and wide range of oxidation states. This chapter discusses the general properties of transition metals and how they differ from the main group elements.
**Chapter 20: d-Metal Complexes: Electronic Structure and Properties**
Building on the previous chapter, Chapter 20 dives deeper into the electronic structure and properties of d-metal complexes, exploring topics such as crystal field theory and ligand field theory. These theories help explain the color, magnetism, and stability of transition metal complexes.
**Chapter 21: Coordination Chemistry: Reactions of Complexes**
Chapter 21 explores the reactions of coordination complexes, including ligand substitution, electron transfer, and catalysis. The reactivity of these complexes is central to understanding many industrial and biological processes.
**Chapter 22: d-Metal Organometallic Chemistry**
In Chapter 22, the focus shifts to the chemistry of organometallic compounds, where transition metals are bonded to carbon-containing ligands. Organometallic chemistry is of great importance in catalysis and materials science.
Chapter 23: The f-Block Metals
The final chapter of Part 2, Chapter 23, introduces the f-block elements, which include the lanthanides and actinides. These elements are known for their unique electronic properties and applications in areas such as nuclear energy and advanced materials.
Part 3: Frontiers
The third and final part of the book, “Frontiers,” explores advanced topics in inorganic chemistry that are at the cutting edge of research.
Chapter 24: Solid-State and Materials Chemistry
Chapter 24 covers solid-state chemistry and the materials science of inorganic compounds, focusing on the structure, properties, and applications of advanced materials.
Chapter 25: Nanomaterials, Nanoscience, and Nanotechnology
Chapter 25 explores the rapidly growing field of nanotechnology, where inorganic compounds play a crucial role in the development of nanomaterials for use in electronics, medicine, and energy storage.
Chapter 26: Catalysis
Chapter 26 discusses catalysis, highlighting the role of inorganic compounds in catalytic processes, both in industry and in biological systems.
Chapter 27: Biological Inorganic Chemistry
Finally, Chapter 27 explores the role of inorganic chemistry in biology, focusing on metalloproteins, metal ion transport, and the function of metals in enzymes and other biological systems.
Resource Sections
Following the main chapters, several resource sections provide supplementary information on topics like ionic radii, electronic properties, standard potentials, symmetry-adapted orbitals, and Tanabe–Sugano diagrams, offering useful tools for students and professionals alike.
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