Coordination Chemistry By Fred Basolo and Ronald C. Johnson (informative)
Free download Coordination Chemistry By Fred Basolo and Ronald C. Johnson
Authors of: Coordination Chemistry By Fred Basolo and Ronald C. Johnson
Fred Basolo
Ronald C. Johnson
Table of Contents in Coordination Chemistry By Fred Basolo and Ronald C. Johnson
Coordination chemistry is a fundamental and dynamic branch of inorganic chemistry that explores the complex interactions between metal ions and ligands. The field, which has grown significantly over the past century, plays a critical role in understanding the structure, bonding, reactivity, and properties of coordination compounds. From its historical roots in Alfred Werner’s revolutionary theories to its modern applications in catalysis, medicine, and material science, coordination chemistry bridges the gap between theoretical models and practical innovations.
Fred Basolo and Ronald C. Johnson’s “Coordination Chemistry” serves as a comprehensive guide for students, researchers, and professionals seeking an in-depth understanding of this essential field. The book offers a balanced approach, blending theoretical foundations with experimental techniques, to provide a holistic view of the subject. Its clear explanations, illustrative diagrams, and well-structured content make it accessible to both beginners and seasoned chemists.
The text begins with a historical overview of coordination chemistry, introducing the key figures, discoveries, and conceptual breakthroughs that shaped the discipline. It then delves into the core principles of coordination compounds, including their nomenclature, isomerism, and electronic structure. Special emphasis is placed on the theories of bonding, such as crystal field theory (CFT) and molecular orbital theory (MOT), which form the basis for understanding the properties and reactivity of these compounds.
Beyond the theoretical framework, the authors explore the kinetic and thermodynamic aspects of coordination reactions, offering readers insight into the mechanisms of ligand substitution, electron transfer, and redox processes. This knowledge is essential for understanding the catalytic properties of coordination complexes, which have profound implications in industrial and biological systems. Through detailed case studies and real-world examples, the book highlights the role of coordination chemistry in key applications, such as homogeneous catalysis, bioinorganic processes, and drug design.
What sets this book apart is its pedagogical approach. Basolo and Johnson present complex concepts with clarity, using logical progression to ensure that readers build a strong conceptual foundation before tackling more advanced topics. Thought-provoking exercises, practical problems, and self-assessment questions are included at the end of each chapter to reinforce learning.
In summary, “Coordination Chemistry” by Fred Basolo and Ronald C. Johnson is a seminal work that continues to inspire and educate generations of chemists. By bridging historical perspectives with contemporary applications, the book provides readers with a profound appreciation for the impact of coordination chemistry on science and society. It is an essential resource for those who wish to master this ever-evolving field and explore the vast possibilities it offers for future discovery and innovation.
The Authors
Preface
Periodic Table
1. Introduction and Historical Development
1.1 Introduction
1.2 Historical development
1.3 Nomenclature
Problems
2. The Coordinate Bond
2.1 The electron-pair bond
2.2 Electronic structure of the atom
2.3 The concept of effective atomic number
2.4 Valence bond theory
2.5 Crystal field theory
2.6 Molecular orbital theory
Problems
3. Stereochemistry
3.1 Geometry of coordination compounds
3.2 Complexes with unusual structural features
3.3 Isomerism in metal complexes
Problems
4. Preparations and Reactions of Coordination Compounds
4.1 Substitution reactions in aqueous solution
4.2 Substitution reactions in nonaqueous solvents
4.3 Substitution reactions in the absence of solvents
4.4 Thermal dissociation of solid complexes
4.5 Photochemical synthesis
4.6 Oxidation–reduction reactions
4.7 Catalysis
4.8 Substitution reactions without metal–ligand bond cleavage
4.9 Trans effect
4.10 Synthesis of cis–trans isomers
4.11 Preparation of optically-active compounds
Problems
5. Complex Ion Stability
5.1 Stability constants
5.2 Factors that influence complex stability
5.3 Stabilization of unusual oxidation states by coordination
5.4 Determination of stability constants
Problems
6. Kinetics and Mechanisms of Reactions of Coordination Compounds
6.1 Rate of a reaction
6.2 The rate law
6.3 Effective collisions
6.4 Inert and labile complexes
6.5 Mechanisms of substitution reactions
6.6 Octahedral substitution reactions
6.7 Square planar substitution
6.8 Mechanisms for redox reactions
Problems
7. Organometallic Chemistry and Current Research Topics
7.1 Preparation of metal carbonyls and organometallic compounds
7.2 Organometallic reactions and homogeneous catalysis
7.3 Metals in living systems
7.4 Solid state chemistry
Problems
Index of Complexes
Index
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