Arene Chemistry by Jacques Mortier
Free Download Arene Chemistry by Jacques Mortier
Reaction Mechanisms and Methods for Aromatic Compounds
Table of Contents
PART I ELECTROPHILIC AROMATIC SUBSTITUTION 1
1 Electrophilic Aromatic Substitution: Mechanism 3
2 Friedel–Crafts Alkylation of Arenes in Total Synthesis
3 Catalytic Friedel–Crafts Acylation Reactions 59
4 The Use of Quantum Chemistry for Mechanistic Analyses of SEAr Reactions
5 Catalytic Enantioselective Electrophilic Aromatic Substitutions 107
PART II NUCLEOPHILIC AROMATIC SUBSTITUTION 131
6 Nucleophilic Aromatic Substitution: An Update Overview
7 Theoretical and Experimental Methods for the Analysis of Reaction Mechanisms in SNAr Processes: Fugality, Philicity, and Solvent Effects 175
8 Asymmetric Nucleophilic Aromatic Substitution 195
9 Homolytic Aromatic Substitution 219
10 Radical‐Nucleophilic Aromatic Substitution 243
11 Nucleophilic Substitution of Hydrogen in Electron‐Deficient Arenes 269
PART III ARYNE CHEMISTRY 299
12 The Chemistry of Arynes: An Overview
PART IV REDUCTION, OXIDATION, AND DEAROMATIZATION REACTIONS 337
13 Reduction/Hydrogenation of Aromatic Rings 339
14 Selective Oxidation of Aromatic Rings
15 Dearomatization Reactions: An Overview 399
PART V AROMATIC REARRANGEMENTS 425
16 Aromatic Compounds via Pericyclic Reactions
17 Ring‐Closing Metathesis: Synthetic Routes to Carbocyclic Aromatic Compounds using Ring‐Closing Alkene and Enyne Metathesis 451
18 Aromatic Rearrangements in which the Migrating Group Migrates to the Aromatic Nucleus: An Overview
Arene Chemistry by Jacques Mortier
PART VI TRANSITION METAL‐MEDIATED COUPLING 511
19 Transition Metal‐Catalyzed Carbon–Carbon Cross‐Coupling 513
20 Transition Metal‐Mediated Carbon–Heteroatom Cross‐Coupling (C─N, C─O, C─S, C─Se, C─Te, C─P, C─As, C─Sb, and C─B Bond Forming Reactions): An Overview 547
21 Transition Metal‐Mediated Aromatic Ring Construction 587
22 Ar–C Bond Formation by Aromatic Carbon–Carbon ipso‐Substitution Reaction 615
PART VII C─H FUNCTIONALIZATION 645
23 Chelate‐Assisted Arene C–H Bond Functionalization 647
24 Reactivity and Selectivity in Transition Metal‐Catalyzed, Nondirected Arene Functionalizations 675
25 Functionalization of Arenes via C─H Bond Activation Catalysed by Transition Metal Complexes: Synergy between Experiment and Theory 715
PART VIII DIRECTED METALATION REACTIONS 741
26 Directed Metalation of Arenes with Organolithiums, Lithium Amides, and Superbases 743
27 Deprotonative Metalation Using Alkali Metal–Nonalkali Metal Combinations 777
28 The Halogen/Metal Interconversion and Related Processes (M = Li, Mg)
PART IX PHOTOCHEMICAL REACTIONS 835
29 Aromatic Photochemical Reactions 837
30 Photochemical Bergman Cyclization and Related Reactions 869
31 Photo‐Fries Reaction and Related Processes 889
PART X BIOTRANSFORMATIONS 913
32 Biotransformations of Arenes: An Overview
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