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Advanced Organic Chemistry Reaction Mechanisms by Reinhard Bruckner

Advanced Organic Chemistry Reaction Mechanisms by Reinhard Bruckner

Advanced Organic Chemistry Reaction Mechanisms by Reinhard Bruckner

Free Download Advanced Organic Chemistry Reaction Mechanisms by Reinhard Bruckner

Advanced Organic Chemistry Reaction Mechanisms by Reinhard Bruckner

Authors:
Reinhard Bruckner

 

Table of Contents

Foreword,

Preface to the English Edition,

Preface to the German Edition,

Acknowledgments,

1 -Radical Substitution Reactions at the Saturated C Atom,

2 -Nucleophilic Substitution Reactions at the Saturated C Atom,

3 -Additions to the Olefinic C=C Double Bond,

4 -β-Eliminations

5 -Substitution Reactions on Aromatic Compounds,

6 -Nucleophilic Substitution Reactions on the Carboxyl Carbon (Except through Enolates),

7 -Additions of Heteroatom Nucleophiles to Heterocumulenes. Additions of Heteroatom

Nucleophiles to Carbonyl Compounds and Follow-up Reactions,

8 -Addition of Hydride Donors and Organometallic Compounds to Carbonyl Compounds,

9 -Reaction of Ylides with Saturated or α,β-Unsaturated Carbonyl Compounds,

10 -Chemistry of the Alkaline Earth Metal Enolates, 11 -Rearrangements,

12 -Thermal Cycloadditions,

13 -Transition Metal-Mediated Alkenylations, Arylations, and Alkynylations,

14 -Oxidations and Reductions,

Subject Index,

Preface to the English Edition

Writing a textbook at any level is always a challenge. In organic chemistry, exciting new discoveries are being made at an ever-increasing pace. However, students of the subject still arrive in the classroom knowing only what they have been taught, often less. The challenge is to present appropriate review material, present venerable, classic chemistry while dealing with the latest results, and, most importantly, provoke thought and discussion. At the time this book was written, there was a need for an advanced text that incorporated these aspects of our science.

The German version of the text was designed for second and third-year chemistry majors: 60–70% of the contents of this book address students before the “Diplomchemiker- Vorexamen,” while the remaining 30–40% address them thereafter. The German book is typically used one year after a standard introductory textbook such as that by Vollhardt and Schore, Streitweiser and Heathcock, or McMurry. Accordingly, in the United States, this text can be used in a class for advanced undergraduates or beginning graduate students. Curricula of other English-speaking countries should allow the use of this text with optimum benefit at a similar point of progress. A good understanding of the fundamentals of organic and physical chemistry will suffice as a foundation for using this textbook to its advantage.

The approach taken in this book conveys the message that the underlying theory of organic chemistry pervades the entire science. It is not necessary at this level to restrict the learning of reactions and mechanisms to any particular order. MO theory and formalisms such as electron pushing with arrows are powerful tools that can be

applied not only to the classic chemistry that led to their development but also to the most recently developed reactions and methods, even those that use transition metals.

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