A Q&A Approach to Organic Chemistry (informative book)
Free download A Q&A Approach to Organic Chemistry
Authors of: A Q&A Approach to Organic Chemistry
Micheal B. Smith
Table of Contents in A Q&A Approach to Organic Chemistry
Preface
Common Abbreviations
Author
Part A A Q&A Approach to Organic Chemistry
1 Orbitals and Bonding
1.1 ORBITALS
1.1.1 Atomic Orbitals
1.1.2 Electron Confguration
1.1.3 Molecular Orbitals
1.2 BONDING
1.2.1 Ionic Bonding
1.2.2 Covalent Bonding
1.3 HYBRIDIZATION
1.4 RESONANCE
END OF CHAPTER PROBLEMS
2 Structure of Molecules
2.1 BASIC STRUCTURE OF ORGANIC MOLECULES
2.1.1 Fundamental Structures
2.1.2 Structures with Other Atoms Bonded to Carbon
2.2 THE VSEPR MODEL AND MOLECULAR GEOMETRY
2.3 DIPOLE MOMENT
2.4 FUNCTIONAL GROUPS
2.5 FORMAL CHARGE
2.6 PHYSICAL PROPERTIES
END OF CHAPTER PROBLEMS
3 Acids and Bases
3.1 ACIDS AND BASES
3.2 ENERGETICS
3.3 THE ACIDITY CONSTANT, Ka
3.4 STRUCTURAL FEATURES THAT INFLUENCE ACIDITY
3.5 FACTORS THAT CONTRIBUTE TO MAKING THE ACID MORE ACIDIC
END OF CHAPTER PROBLEMS
4 Alkanes, Isomers, and Nomenclature
4.1 DEFINITION AND BASIC NOMENCLATURE
4.2 STRUCTURAL ISOMERS
4.3 IUPAC NOMENCLATURE
4.4 CYCLIC ALKANES
END OF CHAPTER PROBLEMS
5 Conformations
5.1 ACYCLIC CONFORMATIONS
5.2 CONFORMATIONS OF CYCLIC MOLECULES
END OF CHAPTER PROBLEMS
6 Stereochemistry
6.1 CHIRALITY
6.2 SPECIFIC ROTATION
6.3 SEQUENCE RULES
6.4 DIASTEREOMERS
6.5 OPTICAL RESOLUTION
END OF CHAPTER PROBLEMS
7 Alkenes and Alkynes: Structure, Nomenclature, and Reactions
7.1 STRUCTURE OF ALKENES
7.2 NOMENCLATURE OF ALKENES
7.3 REACTIONS OF ALKENES
7.4 REACTION OF ALKENES WITH LEWIS ACID-TYPE REAGENTS
7.4.1 Hydroxylation
7.4.2 Epoxidation
7.4.3 Dihydroxylation
7.4.4 Halogenation
7.4.5 Hydroboration
7.5 STRUCTURE AND NOMENCLATURE OF ALKYNES
7.6 REACTIONS OF ALKYNES
END OF CHAPTER PROBLEMS
8 Alkyl Halides and Substitution Reactions
8.1 STRUCTURE, PROPERTIES, AND NOMENCLATURE OF ALKYL HALIDES
8.2 SECOND-ORDER NUCLEOPHILIC SUBSTITUTION (SN2) REACTIONS
8.3 OTHER NUCLEOPHILES IN SN2 REACTIONS
8.4 FIRST-ORDER SUBSTITUTION (SN1) REACTIONS
8.5 COMPETITION BETWEEN SN2 vs. SN1 REACTIONS
8.6 RADICAL HALOGENATION OF ALKANES
END OF CHAPTER PROBLEMS
9 Elimination Reactions
9.1 THE E2 REACTION
9.2 THE E1 REACTION
9.3 PREPARATION OF ALKYNES
9.4 SYN ELIMINATION
END OF CHAPTER PROBLEMS
10 Organometallic Compounds
10.1 ORGANOMETALLICS
10.2 ORGANOMAGNESIUM COMPOUNDS
10.3 ORGANOLITHIUM COMPOUNDS
10.4 BASICITY
10.5 REACTION WITH EPOXIDES
10.6 OTHER METALS
END OF CHAPTER PROBLEMS
11 Spectroscopy
11.1 THE ELECTROMAGNETIC SPECTRUM
11.2 MASS SPECTROMETRY
11.3 INFRARED SPECTROSCOPY (IR)
11.4 NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY (nmr)
END OF CHAPTER PROBLEMS
12 Aldehydes and Ketones. Acyl Addition Reactions
12.1 STRUCTURE AND NOMENCLATURE OF ALDEHYDES AND KETONES
12.2 REACTION OF ALDEHYDES AND KETONES WITH WEAK NUCLEOPHILES
12.3 REACTIONS OF ALDEHYDES AND KETONES. STRONG NUCLEOPHILES
12.4 THE WITTIG REACTION
END OF CHAPTER PROBLEMS
Part B A Q&A Approach to Organic Chemistry
13 Oxidation Reactions
13.1 OXIDATION REACTIONS OF ALKENES
13.2 OXIDATION OF ALKENES: EPOXIDATION
13.3 OXIDATIVE CLEAVAGE: OZONOLYSIS
13.4 OXIDATIVE CLEAVAGE. PERIODIC ACID CLEAVAGE OF 1,2-DIOLS
13.5 OXIDATION OF ALCOHOLS TO ALDEHYDES OR KETONES
END OF CHAPTER PROBLEMS
14 Reduction Reactions
14.1 CATALYTIC HYDROGENATION
14.2 DISSOLVING METAL REDUCTION: ALKYNES
14.3 HYDRIDE REDUCTION OF ALDEHYDES AND KETONES
14.4 CATALYTIC HYDROGENATION AND DISSOLVING METAL REDUCTIONS
ALDEHYDES AND KETONES
END OF CHAPTER PROBLEMS
15 Carboxylic Acids, Carboxylic Acid Derivatives, and Acyl Substitution Reactions
16 Benzene, Aromaticity, and Benzene Derivatives
17 Enolate Anions and Condensation Reactions
18 Conjugation and Reactions of Conjugated Compounds
19 Amines
20 Amino Acids, Peptides, and Proteins
21 Carbohydrates and Nucleic Acids
Appendix: Answers to End of Chapter Problems
Index
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